{"id":73378,"date":"2021-06-29T14:07:53","date_gmt":"2021-06-29T05:07:53","guid":{"rendered":"https:\/\/www.waseda.jp\/top\/?p=73378"},"modified":"2021-06-29T14:08:08","modified_gmt":"2021-06-29T05:08:08","slug":"1%e5%88%86%e3%81%a7%e8%a3%85%e7%9d%80%e5%8f%af%e8%83%bd%e3%80%81%e8%85%b0%e3%81%a0%e3%81%91%e3%81%a7%e3%81%aa%e3%81%8f%e8%85%95%e3%81%ae%e8%b2%a0%e6%8b%85%e3%82%82%e8%bb%bd%e6%b8%9b%e3%81%99-2-3-4-37","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/top\/news\/73378","title":{"rendered":"\u60aa\u81ed\u554f\u984c\u3092\u89e3\u6c7a\u3067\u304d\u308b\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210"},"content":{"rendered":"<h2>\u60aa\u81ed\u554f\u984c\u306b\u89e3\u6c7a\u7b56\u3000\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3092\u5229\u7528\u3057\u305f\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210\u6cd5\u306e\u958b\u767a<br 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href=\"https:\/\/pubs.acs.org\/journal\/jacsat\">Journal of the American Chemical Society<\/a>\u300f\u306e\u30aa\u30f3\u30e9\u30a4\u30f3\u7248\u306b2021\u5e746\u670828\u65e5\uff08\u6708\uff09\uff08\u73fe\u5730\u6642\u9593\uff09\u306b\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<p>\u8ad6\u6587\u540d\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c04215\">Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction<\/a> 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loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-73392 alignnone\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2021\/06\/2b530e80c7d0de90885e285c5d798063-1.png\" alt=\"\" width=\"587\" height=\"228\" \/><\/p>\n<h4>(3)\u305d\u306e\u305f\u3081\u306b\u65b0\u3057\u304f\u958b\u767a\u3057\u305f\u624b\u6cd5<\/h4>\n<p>\u672c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f2020\u5e742\u6708\u306b\u3001\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3092\u5229\u7528\u3057\u305f\u4e16\u754c\u521d\u306e\u30a8\u30b9\u30c6\u30eb\u5408\u6210\u6cd5\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u307e\u3057\u305f \uff08\u53c2\u7167: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.0c00291\">https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.0c00291<\/a>\uff09\u3002<\/p>\n<p>\u4eca\u56de\u3001\u3053\u306e\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3067\u5f97\u3089\u308c\u305f\u77e5\u898b\u3092\u5fdc\u7528\u3059\u308c\u3070\u3001\u30c1\u30aa\u30fc\u30eb\u3092\u7528\u3044\u306a\u3044\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210\u304c\u5b9f\u73fe\u3067\u304d\u308b\u3068\u8003\u3048\u307e\u3057\u305f\u3002\u81a8\u5927\u306a\u53cd\u5fdc\u6761\u4ef6\u691c\u8a0e\u306e\u7d50\u679c\u3001\u7814\u7a76\u5ba4\u3067\u958b\u767a\u3057\u305f\u30cb\u30c3\u30b1\u30eb\u89e6\u5a92\uff08Ni\/dcypt\uff09\u3092\u7528\u3044\u3001\u30d4\u30ea\u30b8\u30eb\u30b9\u30eb\u30d5\u30a3\u30c9\u3092\u30b9\u30eb\u30d5\u30a3\u30c9\u5316\u5264\u3068\u3059\u308b\u3053\u3068\u3067\u7a2e\u3005\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\uff08\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u3001\u30d5\u30a7\u30ce\u30fc\u30eb\u8a98\u5c0e\u4f53\u3001\u82b3\u9999\u65cf\u30cf\u30ed\u30b2\u30f3\u5316\u7269\uff09\u3068\u306e\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u304c\u9032\u884c\u3057\u65b0\u305f\u306a\u82b3\u9999\u65cf\u30b9\u30eb\u30d5\u30a3\u30c9\u304c\u751f\u6210\u3059\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u307e\u3057\u305f\u3002<\/p>\n<p><a href=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2021\/06\/c8856789ec11ab8b1013037cef6929f9.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-73393 size-full\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2021\/06\/c8856789ec11ab8b1013037cef6929f9.png\" alt=\"\" width=\"591\" height=\"309\" \/><\/a><\/p>\n<h4>(4)\u7814\u7a76\u306e\u6ce2\u53ca\u52b9\u679c\u3084\u793e\u4f1a\u7684\u5f71\u97ff<\/h4>\n<p>\u4eca\u56de\u958b\u767a\u3057\u305f\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210\u6cd5\u306f\u30c1\u30aa\u30fc\u30eb\u3092\u4f7f\u7528\u3057\u306a\u3044\u305f\u3081\u3001\u305d\u306e\u60aa\u81ed\u3084\u6bd2\u6027\u554f\u984c\u3092\u89e3\u6c7a\u3067\u304d\u307e\u3059\u3002\u307e\u305f\u3001\u5b89\u4fa1\u3067\u5bb9\u6613\u306b\u5165\u624b\u53ef\u80fd\u306a\u69d8\u3005\u306a\u82b3\u9999\u65cf\u5316\u5408\u7269\u3092\u5909\u63db\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u3001\u533b\u85ac\u54c1\u5316\u5408\u7269\u306e\u76f4\u63a5\u5909\u63db\u306b\u3082\u5229\u7528\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u74b0\u5883\u8abf\u548c\u306b\u512a\u308c\u305f\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u3084\u30d5\u30a7\u30ce\u30fc\u30eb\u8a98\u5c0e\u4f53\u3092\u539f\u6599\u306b\u3067\u304d\u308b\u70b9\u3084\u3001\u8abf\u88fd\u3084\u53d6\u6271\u3044\u304c\u5bb9\u6613\u306a\u30d4\u30ea\u30b8\u30eb\u30b9\u30eb\u30d5\u30a3\u30c9\u3092\u30b9\u30eb\u30d5\u30a3\u30c9\u5316\u5264\u306b\u3067\u304d\u308b\u70b9\u304b\u3089\u7814\u7a76\u5ba4\u30b9\u30b1\u30fc\u30eb\u306f\u3082\u3061\u308d\u3093\u3001\u5de5\u696d\u898f\u6a21\u3067\u306e\u5fdc\u7528\u3082\u671f\u5f85\u3067\u304d\u307e\u3059\u3002<\/p>\n<h4>(5)\u4eca\u5f8c\u306e\u8ab2\u984c<\/h4>\n<p>\u9069\u7528\u53ef\u80fd\u306a\u5316\u5408\u7269\u3082\u591a\u304f\u975e\u5e38\u306b\u30e6\u30cb\u30fc\u30af\u306a\u65b9\u6cd5\u3067\u3042\u308b\u3082\u306e\u306e\u3001\u53cd\u5fdc\u306b\u9ad8\u6e29\u3092\u5fc5\u8981\u3068\u3059\u308b\u3053\u3068\u304c\u4eca\u5f8c\u306e\u8ab2\u984c\u3067\u3059\u3002\u53cd\u5fdc\u306f\u307e\u3060\u767a\u898b\u3055\u308c\u305f\u3070\u304b\u308a\u3067\u3042\u308b\u305f\u3081\u3001\u4eca\u5f8c\u3001\u3088\u308a\u7dbf\u5bc6\u306a\u89e6\u5a92\u6539\u5909\u3001\u53cd\u5fdc\u6761\u4ef6\u306e\u691c\u8a0e\u306b\u3088\u308a\u3001\u3053\u308c\u3089\u306e\u8ab2\u984c\u3092\u514b\u670d\u3057\u305f\u3044\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n<h4>(6)\u7814\u7a76\u8005\u306e\u30b3\u30e1\u30f3\u30c8<\/h4>\n<p>\u5b89\u4fa1\u306b\u5f97\u3089\u308c\u308b\u82b3\u9999\u65cf\u5316\u5408\u7269\u3092\u6709\u7528\u5316\u5408\u7269\u306b\u5909\u63db\u3059\u308b\u65b0\u5947\u53cd\u5fdc\u306e\u958b\u767a\u3092\u7d99\u7d9a\u3057\u3066\u884c\u3063\u3066\u304d\u307e\u3057\u305f\u30023\u3064\u306e\u65b0\u3057\u3044\u53cd\u5fdc\u5f62\u5f0f\u3092\u958b\u767a\u3057\u3001\u305d\u306e\uff11\u3064\u304c\u3053\u306e\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3067\u3059\u3002\u3059\u3067\u306b\u53cd\u5fdc\u306e\u30b3\u30f3\u30bb\u30d7\u30c8\u306f\u6628\u5e74\u5831\u544a\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u304c\u3001\u6709\u7528\u5316\u5408\u7269\u306b\u5909\u63db\u3059\u308b\u3068\u3044\u3046\u8ab2\u984c\u3092\u4e57\u308a\u8d8a\u3048\u305f\u306e\u304c\u672c\u7814\u7a76\u306e\u6210\u679c\u3068\u306a\u308a\u307e\u3059\u3002\u4e00\u8272\u3055\u3093\u3001\u9ed2\u6fa4\u3055\u3093\u306e\u6d3b\u8e8d\u304c\u306a\u3051\u308c\u3070\u3053\u306e\u8003\u3048\u3092\u5b9f\u73fe\u3059\u308b\u306b\u306f\u81f3\u308a\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u4eca\u5f8c\u3082\u3001\u3042\u3063\u3068\u9a5a\u304f\u3088\u3046\u306a\u9ad8\u96e3\u5ea6\u6709\u6a5f\u53cd\u5fdc\u3092\u958b\u767a\u3057\u3066\u3044\u304d\u305f\u3044\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n<h4>(7)\u7528\u8a9e\u89e3\u8aac<\/h4>\n<p>\u203b1\u3000\u82b3\u9999\u74b0<br \/>\n\u30d9\u30f3\u30bc\u30f3\u74b0\u3092\u3082\u3064\u74b0\u72b6\u69cb\u9020\u3002\u3053\u308c\u3089\u3092\u3082\u3064\u6709\u6a5f\u5316\u5408\u7269\u3092\u82b3\u9999\u65cf\u5316\u5408\u7269\u3068\u3044\u3046\u3002\u82b3\u9999\u65cf\u5316\u5408\u7269\u306f\u7279\u6709\u306e\u9999\u308a\u3092\u767a\u3059\u308b\u3002<\/p>\n<p>\u203b2\u3000\u82b3\u9999\u65cf\u30b9\u30eb\u30d5\u30a3\u30c9<br \/>\n\u82b3\u9999\u74b0\u306b\u30e1\u30eb\u30ab\u30d7\u30c8\u57fa\uff08SR\uff09\u304c\u3064\u3044\u305f\u3082\u306e\u3002\u533b\u8fb2\u85ac\u3084\u6a5f\u80fd\u6027\u6750\u6599\u306b\u7528\u3044\u3089\u308c\u308b\u3002<\/p>\n<p>\u203b3\u3000\u30c1\u30aa\u30fc\u30eb<br \/>\n\u672b\u7aef\u306b\u6c34\u7d20\u5316\u3055\u308c\u305f\u786b\u9ec4\u3092\u3082\u3064\u6709\u6a5f\u5316\u5408\u7269\uff08HSR\uff09\u3002\u60aa\u81ed\u3092\u3082\u3064\u3002<\/p>\n<p>\u203b4\u3000\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc<br \/>\n2\u7a2e\u985e\u4ee5\u4e0a\u306e\u82b3\u9999\u74b0\uff08\u30a2\u30ea\u30fc\u30eb\uff09\u3092\u4ea4\u63db\u3059\u308b\u3053\u3068\u3002\u6982\u5ff5\u306f\u5358\u7d14\u3067\u306f\u3042\u308b\u304c\u3001\u5b9f\u969b\u306f\u4e92\u3044\u306e\u82b3\u9999\u74b0\u3092\u540c\u6642\u306b\u53cd\u5fdc\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u89e6\u5a92\u304c\u5fc5\u8981\u3067\u3042\u308b\u3002<\/p>\n<p>\u203b5\u3000S<sub>N<\/sub>2\u53cd\u5fdc<br \/>\n\u6709\u6a5f\u5316\u5b66\u306b\u304a\u3051\u308b\u4e00\u822c\u7684\u306a\u53cd\u5fdc\u5f62\u5f0f\u306e\u4e00\u3064\u3002\u4e8c\u3064\u306e\u5316\u5408\u7269\u304c\u7d50\u5408\u306e\u5207\u65ad\u3092\u4f34\u3044\u306a\u304c\u3089\u65b0\u305f\u306a\u7d50\u5408\u3092\u4f5c\u308a\u51fa\u3059\u53cd\u5fdc\u3002<\/p>\n<p>\u203b6\u3000\u30af\u30ed\u30b9\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u53cd\u5fdc<br \/>\n\u91d1\u5c5e\u89e6\u5a92\u3092\u7528\u3044\u3066\u4e8c\u7a2e\u985e\u306e\u5316\u5408\u7269\u3092\u9023\u7d50\u3055\u305b\u308b\u53cd\u5fdc\u30022010\u5e74\u306e\u30ce\u30fc\u30d9\u30eb\u5316\u5b66\u8cde\u306b\u3082\u9078\u3070\u308c\u3066\u3044\u308b\u3002<\/p>\n<h4>(8)\u8ad6\u6587\u60c5\u5831<\/h4>\n<p>\u96d1\u8a8c\u540d\uff1a<a href=\"https:\/\/pubs.acs.org\/journal\/jacsat\">Journal of the American Chemical Society<\/a><br \/>\n\u8ad6\u6587\u540d\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c04215\">Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction<\/a> \uff08\u30cb\u30c3\u30b1\u30eb\u89e6\u5a92\u306b\u3088\u308b\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3092\u5229\u7528\u3057\u305f\u82b3\u9999\u65cf\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210\uff09<br \/>\n\u8457\u8005\uff1aRyota Isshiki, Miki B. Kurosawa, Kei Muto, and Junichiro Yamaguchi\uff08\u4e00\u8272\u907c\u5927\u3001\u9ed2\u6fa4\u7f8e\u6a39\u3001<a href=\"https:\/\/w-rdb.waseda.jp\/html\/100001441_ja.html\">\u6b66\u85e4\u6176<\/a>\u3001<a href=\"https:\/\/w-rdb.waseda.jp\/html\/100001406_ja.html\">\u5c71\u53e3\u6f64\u4e00\u90ce<\/a>\uff09<br \/>\n\u63b2\u8f09\u65e5\uff08\u73fe\u5730\u6642\u9593\uff09\uff1a2021\u5e746\u670828\u65e5\uff08\u6708\uff09<br \/>\nDOI\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c04215\">10.1021\/jacs.1c04215<\/a><br \/>\n\u63b2\u8f09URL\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c04215\">https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c04215<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u60aa\u81ed\u554f\u984c\u306b\u89e3\u6c7a\u7b56\u3000\u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u3092\u5229\u7528\u3057\u305f\u30b9\u30eb\u30d5\u30a3\u30c9\u5408\u6210\u6cd5\u306e\u958b\u767a \uff5e\u72ec\u81ea\u306e\u91d1\u5c5e\u89e6\u5a92\u3067\u30b9\u30eb\u30d5\u30a3\u30c9\u985e\u306e\u82b3\u9999\u74b0\u3092\u4ed8\u3051\u66ff\u3048\u308b\uff5e \u767a\u8868\u306e\u30dd\u30a4\u30f3\u30c8 \u82b3\u9999\u74b0\u4ea4\u63db\u53cd\u5fdc\u306b\u3088\u308a\u82b3\u9999\u65cf\u30b9\u30eb\u30d5\u30a3\u30c9\u90e8\u4f4d\u3092\u4ed6\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u306b\u79fb\u52d5\u3055\u305b\u308b\u3053\u3068\u306b\u6210\u529f\u3002  [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":73491,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[40,1],"tags":[357,204,5],"class_list":["post-73378","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-topic","category-news","tag-pressrelease","tag-highlight","tag-research"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/73378","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/comments?post=73378"}],"version-history":[{"count":2,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/73378\/revisions"}],"predecessor-version":[{"id":73526,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/73378\/revisions\/73526"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media\/73491"}],"wp:attachment":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media?parent=73378"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/categories?post=73378"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/tags?post=73378"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}