{"id":69772,"date":"2020-07-30T14:00:08","date_gmt":"2020-07-30T05:00:08","guid":{"rendered":"https:\/\/www.waseda.jp\/top\/?p=69772"},"modified":"2020-07-30T14:08:09","modified_gmt":"2020-07-30T05:08:09","slug":"%e2%80%bb%e6%8a%95%e7%a8%bf%e5%89%8d%ef%bc%88%e5%b1%b1%e5%8f%a3%e5%85%88%e7%94%9f%e3%83%aa%e3%83%aa%e3%83%bc%e3%82%b97-30%e4%ba%88%e5%ae%9a%ef%bc%89","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/top\/news\/69772","title":{"rendered":"\u30d9\u30f3\u30bc\u30f3\u306a\u3069\u304b\u3089\u4e09\u6b21\u5143\u5206\u5b50\u3092\u5408\u6210"},"content":{"rendered":"<h1><strong>\u30d9\u30f3\u30bc\u30f3\u306a\u3069\u5b89\u4fa1\u306a\u539f\u6599\u304b\u3089\u6709\u7528\u306a\u4e09\u6b21\u5143\u5206\u5b50\u3092\u5408\u6210\u3059\u308b<\/strong><\/h1>\n<h2><strong>\u89e6\u5a92\u7684\u306a\u8131\u82b3\u9999\u65cf\u7684\u4e8c\u70ad\u7d20\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u306e\u958b\u767a\u306b\u6210\u529f<\/strong><\/h2>\n<h3><strong>\u767a\u8868\u306e\u30dd\u30a4\u30f3\u30c8<\/strong><\/h3>\n<h4>\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u306b\u3088\u308a\u30d9\u30f3\u30bc\u30f3\u74b0\u3092\u58ca\u3057\u306a\u304c\u3089\uff12\u3064\u306e\u70ad\u7d20\u2013\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u306b\u6210\u529f<\/h4>\n<h4>\u69d8\u3005\u306a\u5358\u7d14\u82b3\u9999\u65cf\u5316\u5408\u7269(\u5e73\u9762)\u304b\u3089\u8102\u74b0\u5f0f\u5316\u5408\u7269\uff08\u4e09\u6b21\u5143\uff09\u3092\u52b9\u7387\u7684\u306b\u5408\u6210\u53ef\u80fd<\/h4>\n<h4>\u533b\u8fb2\u85ac\u3067\u91cd\u8981\u8996\u3055\u308c\u308b\u6709\u7528\u306a\u4e09\u6b21\u5143\u69cb\u9020\u5206\u5b50\u306e\u65b0\u898f\u5408\u6210\u6cd5\u3092\u63d0\u4f9b<\/h4>\n<p>\u65e9\u7a32\u7530\u5927\u5b66\u9ad8\u7b49\u7814\u7a76\u6240\u306e<a href=\"http:\/\/www.jyamaguchi-lab.com\/member\/kmuto\">\u6b66\u85e4\u6176\uff08\u3080\u3068\u3046\u3051\u3044\uff09\u8b1b\u5e2b<\/a>\u3001\u304a\u3088\u3073\u7406\u5de5\u5b66\u8853\u9662\u306e<a href=\"http:\/\/www.jyamaguchi-lab.com\/\">\u5c71\u53e3\u6f64\u4e00\u90ce\uff08\u3084\u307e\u3050\u3061\u3058\u3085\u3093\u3044\u3061\u308d\u3046\uff09\u6559\u6388<\/a>\u3089\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u3092\u7528\u3044\u3066\u3001\u82b3\u9999\u65cf\u5316\u5408\u7269<strong>\uff08\u203b\uff11\uff09<\/strong>\u3092\u58ca\u3057\u306a\u304c\u3089\uff12\u3064\u306e\u70ad\u7d20\u30fc\u70ad\u7d20\u7d50\u5408\u3092\u3064\u304f\u308b\u300c\u8131\u82b3\u9999\u65cf\u7684\u4e8c\u70ad\u7d20\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\uff08\u4ee5\u4e0b\u3001\u672c\u53cd\u5fdc\uff09\u300d\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u8907\u6570\u306e\u7f6e\u63db\u57fa\u3092\u3082\u3064\u30b7\u30af\u30ed\u30d8\u30ad\u30b5\u30f3\u306a\u3069\u306e\u8102\u74b0\u5f0f\u5316\u5408\u7269<strong>\uff08\u203b2\uff09<\/strong>\u306f\u4e09\u6b21\u5143\u9aa8\u683c\u3092\u3082\u3061\u3001\u533b\u85ac\u54c1\u306b\u3082\u983b\u51fa\u3059\u308b\u91cd\u8981\u306a\u69cb\u9020\u3067\u3059\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u5e73\u9762\u69cb\u9020\u3067\u3042\u308b\u30d9\u30f3\u30bc\u30f3\u306a\u3069\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u3092\u300c\u4e09\u6b21\u5143\u69cb\u9020\u524d\u99c6\u4f53\u300d\u3068\u3057\u3066\u6d3b\u7528\u3059\u3079\u304f\u8131\u82b3\u9999\u65cf\u7684\u5408\u6210\u6cd5\u306e\u958b\u767a\u3092\u76ee\u6307\u3057\u307e\u3057\u305f\u3002\u3057\u304b\u3057\u3001\u82b3\u9999\u65cf\u5316\u5408\u7269\u306f\u3001\u82b3\u9999\u65cf\u5b89\u5b9a\u5316\u52b9\u679c<strong>\uff08\u203b\uff13\uff09<\/strong>\u3092\u3082\u3064\u305f\u3081\u3001\u8131\u82b3\u9999\u65cf\u5316\u306e\u9054\u6210\u306b\u306f\u3053\u306e\u5b89\u5b9a\u5316\u52b9\u679c\u306e\u6253\u7834\u304c\u8ab2\u984c\u3068\u306a\u308a\u307e\u3059\u3002\u3055\u3089\u306b\u8131\u82b3\u9999\u65cf\u5316\u3068\u540c\u6642\u306b\u5316\u5b66\u4fee\u98fe\u3059\u308b\u300c\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u300d\u306f\u3001\u7f6e\u63db\u57fa\u3092\u3082\u3064\u8102\u74b0\u5f0f\u5316\u5408\u7269\u306e\u76f4\u611f\u7684\u306a\u5408\u6210\u6cd5\u3067\u3042\u308b\u3082\u306e\u306e\u3001\u65e2\u5b58\u6cd5\u306f\u3044\u304f\u3064\u3082\u306e\u5236\u7d04\u3092\u8981\u3059\u308b\u305f\u3081\u6700\u9ad8\u96e3\u5ea6\u306e\u5206\u5b50\u5909\u63db\u6cd5\u306e\u4e00\u3064\u3068\u3055\u308c\u3066\u304d\u307e\u3057\u305f\u3002<\/p>\n<p>\u4eca\u56de\u7814\u7a76\u30c1\u30fc\u30e0\u306f\u3001\u82b3\u9999\u65cf\u5316\u5408\u7269\u306b\u5bfe\u3059\u308b\u89e6\u5a92\u7684\u306a\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u306e\u958b\u767a\u3092\u8a66\u307f\u307e\u3057\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u6761\u4ef6\u4e0b\u3001\u30b8\u30a2\u30be\u5316\u5408\u7269<strong>\uff08\u203b4\uff09<\/strong>\u3068\u30de\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u3092\u70ad\u7d20\u5b98\u80fd\u57fa\u5316\u5264\u3068\u3059\u308b\u3053\u3068\u3067\u3001\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3<strong>\uff08\u203b5\uff09<\/strong>\u3092\u8131\u82b3\u9999\u65cf\u3055\u305b\u3001\u540c\u6642\u306b\uff12\u3064\u306e\u70ad\u7d20\u2013\u70ad\u7d20\u7d50\u5408\u3092\u5f62\u6210\u3059\u308b\u672c\u53cd\u5fdc\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u8907\u7d20\u82b3\u9999\u74b0\u3092\u542b\u3080\u69d8\u3005\u306a\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u3067\u672c\u53cd\u5fdc\u304c\u52b9\u7387\u3088\u304f\u9032\u884c\u3057\u307e\u3059\u3002\u672c\u53cd\u5fdc\u306e\u5f8c\u306b\u9084\u5143\u3084\u74b0\u5316\u53cd\u5fdc\u306a\u3069\u7a2e\u3005\u306e\u5316\u5b66\u53cd\u5fdc\u3092\u65bd\u3059\u3053\u3068\u3067\u3001\u9ad8\u5ea6\u306b\u5316\u5b66\u4fee\u98fe\u3055\u308c\u305f\u8102\u74b0\u5f0f\u5206\u5b50\u306e\u77ed\u5de5\u7a0b\u5408\u6210\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u672c\u7814\u7a76\u6210\u679c\u306f\u3001\u82f1\u56fd\u738b\u7acb\u5316\u5b66\u4f1a\u8a8c\u300e<a href=\"https:\/\/www.rsc.org\/journals-books-databases\/about-journals\/chemical-science\/\">Chemical Science<\/a>\u300f\u306b2020\u5e747\u670829\u65e5\uff08\u73fe\u5730\u6642\u9593\uff09\u306b\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<p><strong>\u8ad6\u6587\u540d\uff1a<\/strong><a href=\"https:\/\/doi.org\/10.1039\/D0SC02881A\">Catalytic Three-component C\u2013C Bond Forming Dearomatization of Bromoarenes with Malonates and Diazo Compounds<\/a> \uff08\u30de\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u3068\u30b8\u30a2\u30be\u5316\u5408\u7269\u3092\u7528\u3044\u308b\u82b3\u9999\u65cf\u30d6\u30ed\u30e2\u5316\u5408\u7269\u306e\u89e6\u5a92\u7684\u4e09\u6210\u5206\u70ad\u7d20\u2013\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u8131\u82b3\u9999\u65cf\u5316\u53cd\u5fdc\uff09<\/p>\n<h3><strong>(1)<\/strong><strong>\u3053\u308c\u307e\u3067\u306e\u7814\u7a76\u3067\u5206\u304b\u3063\u3066\u3044\u305f\u3053\u3068<\/strong><\/h3>\n<p>\u533b\u8fb2\u85ac\u5206\u5b50\u306e\u591a\u304f\u306f\u3001\u5408\u6210\u304c\u6bd4\u8f03\u7684\u7c21\u4fbf\u3067\u3042\u308b\u3068\u3044\u3046\u7406\u7531\u304b\u3089\u82b3\u9999\u65cf\u5316\u5408\u7269(\u5e73\u9762\u69cb\u9020)\u3067\u3059\u3002\u3057\u304b\u3057\u3001\u751f\u7269\u306f\u4e09\u6b21\u5143\u306e\u5206\u5b50\u69cb\u9020\u4f53\u3067\u3042\u308a\u3001\u305d\u308c\u3089\u3068\u76f8\u4e92\u4f5c\u7528\u3059\u308b\u5206\u5b50\uff08\u533b\u8fb2\u85ac\uff09\u3082\u6709\u7528\u306a\u751f\u7269\u6d3b\u6027\u3092\u5f97\u308b\u305f\u3081\u306b\u4e09\u6b21\u5143\u69cb\u9020\u304c\u671b\u307e\u3057\u3044\u3068\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u3059\u306a\u308f\u3061\u3001\u52b9\u7387\u7684\u306a\u30d5\u30e9\u30c3\u30c8\u30e9\u30f3\u30c9\u304b\u3089\u306e\u8131\u5374\uff08\u5e73\u9762\u69cb\u9020\u2192\u4e09\u6b21\u5143\u69cb\u9020\uff09\u304c\u73fe\u5728\u5275\u85ac\u73fe\u5834\u3067\u306e\u8ab2\u984c\u3068\u306a\u3063\u3066\u3044\u307e\u3059\u3002\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u82b3\u9999\u65cf\u6027\u3092\u58ca\u3057\u3001\u3059\u306a\u308f\u3061\u5e73\u9762\u69cb\u9020\u3092\u58ca\u3057\u3064\u3064\u305d\u306e\u74b0\u4e0a\u3092\u5316\u5b66\u4fee\u98fe\u3059\u308b\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u306f\u3001\u4e09\u6b21\u5143\u69cb\u9020\u3092\u3082\u3064\u8102\u74b0\u5f0f\u5316\u5408\u7269\u306e\u5408\u6210\u6cd5\u3068\u3057\u3066\u76f4\u63a5\u7684\u304b\u3064\u308f\u304b\u308a\u3084\u3059\u304f\u6975\u3081\u3066\u6709\u7528\u3067\u3059\u3002\u3057\u304b\u3057\u3001\u305d\u308c\u3089\u306e\u53cd\u5fdc\u306f\u9ad8\u3044\u82b3\u9999\u65cf\u5b89\u5b9a\u5316\u52b9\u679c\u306e\u6253\u7834\u3092\u5fc5\u8981\u3068\u3059\u308b\u305f\u3081\u3001\u9ad8\u96e3\u5ea6\u5909\u63db\u6cd5\u3068\u3055\u308c\u3066\u304d\u307e\u3057\u305f\u3002\u7279\u306b\u7f6e\u63db\u30d9\u30f3\u30bc\u30f3\u985e\u306f\u5b89\u5b9a\u306a\u82b3\u9999\u65cf\u5316\u5408\u7269\u3067\u3042\u308a\u3001\u65e2\u5b58\u306e\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u3067\u306f\u904e\u5270\u91cf\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u3084\u6bd2\u6027\u306e\u91d1\u5c5e\u8a66\u85ac\u3092\u4f7f\u7528\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-69773 size-medium\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi-610x225.jpg\" alt=\"\" width=\"610\" height=\"225\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi-610x225.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi-768x283.jpg 768w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi.jpg 1348w\" sizes=\"auto, (max-width: 610px) 100vw, 610px\" \/><\/p>\n<p>\u672c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u3067\u306f\u3053\u308c\u307e\u3067\u306e\u7814\u7a76\u306e\u7d50\u679c\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u3092\u3082\u3061\u3044\u305f\u30d9\u30f3\u30b8\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u985e\u3084\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u306e\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30ea\u30eb\u5316\u53cd\u5fdc<strong>\uff08\u203b6\uff09<\/strong>\u3092\u767a\u898b\u3057\u3066\u3044\u307e\u3059(<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.9b03461\">\u53c2\u7167\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.9b03461<\/a>)\u3002\u3053\u308c\u3089\u306f\u904e\u5270\u91cf\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u3092\u7528\u3044\u305a\u4e00\u5f53\u91cf\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u8131\u82b3\u9999\u65cf\u5316\u3092\u53ef\u80fd\u306b\u3057\u305f\u597d\u4f8b\u3067\u3059\u304c\u3001\u30a2\u30ea\u30eb\u5316\u53cd\u5fdc\u306b\u9650\u3089\u308c\u3066\u3044\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u5f97\u3089\u308c\u305f\u8131\u82b3\u9999\u65cf\u4f53\u306e\u4e0d\u5b89\u5b9a\u3055\u306b\u3088\u308a\u3001\u3053\u308c\u3089\u3092\u5b89\u5b9a\u306a\u4e09\u6b21\u5143\u69cb\u9020\u4f53\u3078\u5909\u63db\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n<h3><strong>(2)<\/strong> <strong>\u4eca\u56de\u306e\u7814\u7a76\u3067\u65b0\u305f\u306b\u5b9f\u73fe\u3057\u3088\u3046\u3068\u3057\u305f\u3053\u3068<\/strong><\/h3>\n<p>\u672c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\uff08\u5927\u5b66\u9662\u5148\u9032\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u4fee\u58eb\u8ab2\u7a0b2\u5e74\u52a0\u85e4\u5f18\u57fa\u3001\u540c\u4fee\u58eb\u8ab2\u7a0b1\u5e74\u6b66\u8005\u6a39\u3001\u540c\u535a\u58eb\u8ab2\u7a0b2\u5e74\u5c0f\u677e\u7530\u96c5\u6643\u3001\u9ad8\u7b49\u7814\u7a76\u6240\u6b66\u85e4\u6176\u8b1b\u5e2b\u3001\u7406\u5de5\u5b66\u8853\u9662\u5c71\u53e3\u6f64\u4e00\u90ce\u6559\u6388\uff09\u306f\u3001\u4e09\u6b21\u5143\u74b0\u72b6\u5206\u5b50\u306e\u52b9\u7387\u7684\u306a\u5408\u6210\u6cd5\u306e\u958b\u767a\u3092\u5fd7\u5411\u3057\u3001\u30a2\u30ea\u30eb\u5316\u5264\u3068\u306f\u7570\u306a\u308b\u70ad\u7d20\u5316\u5264\u3092\u4f7f\u7528\u3057\u3066\u3001\u5b89\u4fa1\u306a\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u3092\u52b9\u7387\u7684\u306b\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u3059\u308b\u65b0\u624b\u6cd5\u306e\u958b\u767a\u306b\u6311\u6226\u3057\u307e\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-69777\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi5-610x359.jpg\" alt=\"\" width=\"450\" height=\"265\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi5-610x359.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi5-768x452.jpg 768w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi5.jpg 952w\" sizes=\"auto, (max-width: 450px) 100vw, 450px\" \/><\/p>\n<h3><strong>(3)<\/strong><strong>\u305d\u306e\u305f\u3081\u306b\u65b0\u3057\u304f\u958b\u767a\u3057\u305f\u624b\u6cd5<\/strong><\/h3>\n<p>\u672c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3053\u308c\u307e\u3067\u3001\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30ea\u30eb\u5316\u53cd\u5fdc\u306b\u306f\u300c\u30a2\u30ea\u30eb-\u30d1\u30e9\u30b8\u30a6\u30e0-\u30d9\u30f3\u30b8\u30eb\u4e2d\u9593\u4f53\u300d\u306e\u767a\u751f\u304c\u91cd\u8981\u3067\u3042\u308b\u3068\u308f\u304b\u3063\u3066\u3044\u307e\u3057\u305f\u3002\u4eca\u56de\u3001\u30a2\u30ea\u30eb\u57fa\u306e\u70ad\u7d20\u539f\u5b50\u3092\u4e00\u3064\u9178\u7d20\u306b\u7f6e\u304d\u63db\u3048\u305f\u5316\u5b66\u7a2e\uff08\u30a8\u30ce\u30e9\u30fc\u30c8\uff09\u3092\u7528\u3044\u3066\u3082\u540c\u69d8\u306b\u53cd\u5fdc\u304c\u9032\u884c\u3057\u3001\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u304c\u3067\u304d\u308b\u3068\u8003\u3048\u307e\u3057\u305f\u3002\u81a8\u5927\u306a\u53cd\u5fdc\u6761\u4ef6\u306e\u7cbe\u67fb\u306e\u7d50\u679c\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u3068\u6c34\u7d20\u5316\u30ca\u30c8\u30ea\u30a6\u30e0\uff08NaH\uff09\u5b58\u5728\u4e0b\u3001\u7a2e\u3005\u306e\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u306b\u5bfe\u3057\u30b8\u30a2\u30be\u5316\u5408\u7269\u3068\u30de\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u3092\u53cd\u5fdc\u5264\u306b\u4f7f\u7528\u3059\u308b\u3068\u72d9\u3044\u306e\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u304c\u9032\u884c\u3057\u3001\u8131\u82b3\u9999\u65cf\u5316\u53cd\u5fdc\u3068\u540c\u6642\u306b\u4e8c\u3064\u306e\u70ad\u7d20\u00ad\u2013\u70ad\u7d20\u7d50\u5408\u304c\u5f62\u6210\u3067\u304d\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-69776\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi4-1.jpg\" alt=\"\" width=\"1000\" height=\"417\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi4-1.jpg 1464w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi4-1-610x254.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi4-1-768x320.jpg 768w\" sizes=\"auto, (max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<h3><strong>(4)<\/strong><strong>\u4eca\u56de\u306e\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f\u7d50\u679c\u53ca\u3073\u77e5\u898b<\/strong><\/h3>\n<p>\u958b\u767a\u3057\u305f\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u306f\u300120\u7a2e\u985e\u4ee5\u4e0a\u306e\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u3092\u8131\u82b3\u9999\u65cf\u7684\u306b\u4e8c\u5b98\u80fd\u57fa\u5316\u3067\u304d\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u672c\u624b\u6cd5\u3067\u5f97\u3089\u308c\u308b\u751f\u6210\u7269\u306b\u5bfe\u3057\u3066\u7a2e\u3005\u306e\u5909\u63db\u53cd\u5fdc\u3092\u65bd\u3059\u3053\u3068\u3067\u3001\u591a\u69d8\u306a\u8102\u74b0\u5f0f\u5316\u5408\u7269\u304c\u5408\u6210\u53ef\u80fd\u306b\u306a\u308a\u307e\u3057\u305f\u3002\u4f8b\u3048\u3070\u3001\u30d6\u30ed\u30e2\u30ca\u30d5\u30bf\u30ec\u30f3\u3092\u51fa\u767a\u539f\u6599\u3068\u3057\u3001\u958b\u767a\u3057\u305f\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u3067\u5f97\u3089\u308c\u308b\u751f\u6210\u7269\u3092\u5909\u63db\u3059\u308b\u3053\u3068\u3067\u3001\u9ad8\u5ea6\u306b\u5316\u5b66\u4fee\u98fe\u3055\u308c\u305f\u8102\u74b0\u5f0f\u5316\u5408\u7269\u304c\u5408\u6210\u3067\u304d\u307e\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-69775\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi3-1.jpg\" alt=\"\" width=\"1000\" height=\"461\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi3-1.jpg 1428w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi3-1-610x281.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/07\/yamaguchi3-1-768x354.jpg 768w\" sizes=\"auto, (max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<h3><strong>(5)<\/strong><strong>\u7814\u7a76\u306e\u6ce2\u53ca\u52b9\u679c\u3084\u793e\u4f1a\u7684\u5f71\u97ff<\/strong><\/h3>\n<p>\u4eca\u56de\u958b\u767a\u3057\u305f\u53cd\u5fdc\u306f\u5bb9\u6613\u306b\u5165\u624b\u53ef\u80fd\u306a\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u3092\u89e6\u5a92\u7684\u306b\u5909\u63db\u3057\u3001\u6709\u7528\u306a\u4e09\u6b21\u5143\u69cb\u9020\u5206\u5b50\u3092\u5408\u6210\u3067\u304d\u307e\u3059\u3002\u672c\u53cd\u5fdc\u306f\u904e\u5270\u91cf\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u3092\u8981\u305b\u305a\u3001\u52b9\u7387\u7684\u3067\u3059\u3002\uff11\u5f53\u91cf\u306e\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\u306b\u5bfe\u3057\u3066\u53cd\u5fdc\u304c\u9032\u884c\u3059\u308b\u305f\u3081\u3001\u4eca\u5f8c\u3001\u533b\u8fb2\u85ac\u5316\u5408\u7269\u306e\u76f4\u63a5\u5909\u63db\u3078\u3068\u5fdc\u7528\u3059\u308c\u3070\u3001\u65b0\u898f\u533b\u85ac\u54c1\u5019\u88dc\u5316\u5408\u7269\u306e\u8fc5\u901f\u63a2\u7d22\u304c\u53ef\u80fd\u306b\u306a\u308b\u3068\u671f\u5f85\u3067\u304d\u307e\u3059\u3002<\/p>\n<h3><strong>(6)<\/strong><strong>\u4eca\u5f8c\u306e\u8ab2\u984c<\/strong><\/h3>\n<p>\u73fe\u72b6\u3001\u9069\u7528\u53ef\u80fd\u306a\u53cd\u5fdc\u5264\u304c\u30de\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u3084\u7279\u5b9a\u306e\u30b8\u30a2\u30be\u5316\u5408\u7269\u306b\u9650\u3089\u308c\u308b\u305f\u3081\u3001\u5408\u6210\u3067\u304d\u308b\u7f6e\u63db\u8102\u74b0\u5f0f\u5316\u5408\u7269\u306e\u62e1\u5927\u306b\u6539\u5584\u306e\u4f59\u5730\u3092\u6b8b\u3057\u307e\u3059\u3002\u4eca\u5f8c\u3001\u65b0\u898f\u89e6\u5a92\u306e\u958b\u767a\u3092\u901a\u3058\u3066\u3001\u3053\u306e\u8ab2\u984c\u3092\u514b\u670d\u3057\u305f\u3044\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n<h3><strong>(7)<\/strong><strong>\u7528\u8a9e\u89e3\u8aac<\/strong><\/h3>\n<p><strong>\u203b1\u3000\u82b3\u9999\u65cf\u5316\u5408\u7269\uff1a<\/strong>\u30d9\u30f3\u30bc\u30f3\u3092\u4ee3\u8868\u3068\u3059\u308b\u74b0\u72b6\u4e0d\u98fd\u548c\u6709\u6a5f\u5316\u5408\u7269\u306e\u3053\u3068\u3002\u5b89\u4fa1\u306b\u5165\u624b\u53ef\u80fd\u3002\u5316\u5b66\u7684\u306b\u5b89\u5b9a\u3067\u3042\u308b\u3002<\/p>\n<p><strong>\u203b2<\/strong><strong>\u3000\u8102\u74b0\u5f0f\u5316\u5408\u7269\uff1a<\/strong>\u30b7\u30af\u30ed\u30d8\u30ad\u30b5\u30f3\u306a\u3069\u306e\u82b3\u9999\u65cf\u6027\u3092\u3082\u305f\u306a\u3044\u74b0\u72b6\u6709\u6a5f\u5316\u5408\u7269\u306e\u3053\u3068\u3002\u9aa8\u683c\u304c\u67d4\u8edf\u3067\u3001\u4e09\u6b21\u5143\u69cb\u9020\u3092\u3082\u3064\u3002<\/p>\n<p><strong>\u203b3<\/strong><strong>\u3000\u82b3\u9999\u65cf\u5b89\u5b9a\u5316\u52b9\u679c\uff1a<\/strong>\u82b3\u9999\u65cf\u5316\u5408\u7269\u304c\u3082\u3064\u74b0\u4e0a\u306e\u30d1\u30a4\u96fb\u5b50\u304c\u975e\u5c40\u5728\u5316\u3059\u308b\u3053\u3068\u3067\u5f97\u3089\u308c\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u7684\u306a\u5b89\u5b9a\u5316\u52b9\u679c\u3002<\/p>\n<p><strong>\u203b4 \u00a0<\/strong><strong>\u30b8\u30a2\u30be\u5316\u5408\u7269\uff1a<\/strong>\u30b8\u30a2\u30be\u30e1\u30bf\u30f3\u3084\u30b8\u30a2\u30be\u9162\u9178\u30a8\u30b9\u30c6\u30eb\u3092\u4ee3\u8868\u3068\u3059\u308b\u3001N<sub>2<\/sub>\u3067\u8868\u3055\u308c\u308b\u30b8\u30a2\u30be\u57fa\u3068\u7d50\u5408\u3057\u305f\u70ad\u7d20\u3092\u3082\u3064\u5206\u5b50\u3002\u6709\u6a5f\u5408\u6210\u3067\u983b\u7528\u3055\u308c\u308b\u3002<\/p>\n<p><strong>\u203b5<\/strong><strong>\u3000\u30d6\u30ed\u30e2\u30a2\u30ec\u30fc\u30f3\uff1a<\/strong>\u81ed\u7d20\u304c\u7d50\u5408\u3057\u3066\u3044\u308b\u82b3\u9999\u65cf\u5316\u5408\u7269\u3002\u5b89\u4fa1\u306b\u5165\u624b\u53ef\u80fd\u3002<\/p>\n<p><strong>\u203b6<\/strong><strong>\u3000\u30a2\u30ea\u30eb\u5316\uff1a<\/strong>C<sub>3<\/sub>H<sub>5<\/sub>\u3067\u8868\u3055\u308c\u308b\u70ad\u7d20\u7f6e\u63db\u57fa\u3092\u5c0e\u5165\u3059\u308b\u53cd\u5fdc\u306e\u3053\u3068\u3002<\/p>\n<h3><strong>(8)<\/strong><strong>\u8ad6\u6587\u60c5\u5831<\/strong><\/h3>\n<p><strong>\u63b2\u8f09\u96d1\u8a8c\uff1a<\/strong><a href=\"https:\/\/www.rsc.org\/journals-books-databases\/about-journals\/chemical-science\/\">Chemical Science\uff08\u30b1\u30df\u30ab\u30eb\u30b5\u30a4\u30a8\u30f3\u30b9\uff09<\/a><strong><br \/>\n<\/strong><strong>\u8ad6\u6587\u540d\uff1a<\/strong><a href=\"https:\/\/doi.org\/10.1039\/D0SC02881A\">Catalytic Three-component C\u2013C Bond Forming Dearomatization of Bromoarenes with Malonates and Diazo Compounds<\/a> \uff08\u30de\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u3068\u30b8\u30a2\u30be\u5316\u5408\u7269\u3092\u7528\u3044\u308b\u82b3\u9999\u65cf\u30d6\u30ed\u30e2\u5316\u5408\u7269\u306e\u89e6\u5a92\u7684\u4e09\u6210\u5206\u70ad\u7d20\u2013\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u8131\u82b3\u9999\u65cf\u5316\u53cd\u5fdc\uff09<br \/>\n<strong>\u8457\u8005\uff1a<\/strong>Hiroki Kato, Itsuki Musha, Masaaki Komatsuda, Kei Muto, and Junichiro Yamaguchi\uff08\u52a0\u85e4\u5f18\u57fa\u3001\u6b66\u8005\u6a39\u3001\u5c0f\u677e\u7530\u96c5\u6643\u3001<a href=\"http:\/\/www.jyamaguchi-lab.com\/member\/kmuto\">\u6b66\u85e4\u6176<\/a>\u3001<a href=\"http:\/\/www.jyamaguchi-lab.com\/\">\u5c71\u53e3\u6f64\u4e00\u90ce<\/a>\uff09<br \/>\n<strong>\u8ad6\u6587\u516c\u958b\u65e5\uff1a<\/strong>2020\u5e747\u670829\u65e5 (\u73fe\u5730\u6642\u9593)<br \/>\n<strong>DOI:<\/strong> <a href=\"https:\/\/doi.org\/10.1039\/D0SC02881A\">https:\/\/doi.org\/10.1039\/D0SC02881A<\/a><br \/>\n<strong>\u63b2\u8f09URL\uff1a<\/strong> <a href=\"https:\/\/doi.org\/10.1039\/D0SC02881A\">https:\/\/doi.org\/10.1039\/D0SC02881A<\/a><\/p>\n<h3><strong>(9)<\/strong><strong>\u7814\u7a76\u52a9\u6210<\/strong><\/h3>\n<p>\u7814\u7a76\u8cbb\u540d\uff1a\u79d1\u5b66\u7814\u7a76\u8cbb\uff1a\u65b0\u5b66\u8853\u9818\u57df\u7814\u7a76<br \/>\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a<a href=\"https:\/\/kaken.nii.ac.jp\/ja\/grant\/KAKENHI-PUBLICLY-20H04829\/\">\u6c42\u6838\u7a2e\u6d3b\u6027\u5316\u578b\u6709\u6a5f\u30fb\u9077\u79fb\u91d1\u5c5e\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u89e6\u5a92\u3092\u7528\u3044\u308b\u8131\u82b3\u9999\u65cf\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u53cd\u5fdc<\/a><br \/>\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\u3000<a href=\"http:\/\/www.jyamaguchi-lab.com\/member\/kmuto\">\u6b66\u85e4\u6176\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n<p>\u7814\u7a76\u8cbb\u540d\uff1a\u79d1\u5b66\u7814\u7a76\u8cbb\uff1a\u82e5\u624b\u7814\u7a76<br \/>\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a<a href=\"https:\/\/kaken.nii.ac.jp\/ja\/grant\/KAKENHI-PROJECT-19K15573\/\">\u914d\u4f4d\u5b50\u306b\u3088\u308b\u53cd\u5fdc\u7a7a\u9593\u5236\u5fa1\u3092\u9375\u3068\u3059\u308b\u89e6\u5a92\u7684\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u306e\u958b\u767a\u3068\u5fdc\u7528<\/a><br \/>\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\u3000<a href=\"http:\/\/www.jyamaguchi-lab.com\/member\/kmuto\">\u6b66\u85e4\u6176\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n<p>\u7814\u7a76\u8cbb\u540d\uff1a\u91cc\u898b\u5968\u5b66\u4f1a\u7814\u7a76\u52a9\u6210<br \/>\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a\u8131\u82b3\u9999\u65cf\u7684\u5b98\u80fd\u57fa\u5316\u306b\u3088\u308b\u300c\u5e73\u9762\u69cb\u9020\u304b\u3089\u306e\u8131\u5374\u300d\u5408\u6210\u6cd5\u306e\u958b\u767a<br \/>\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\u3000<a href=\"http:\/\/www.jyamaguchi-lab.com\/member\/kmuto\">\u6b66\u85e4\u6176\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n<p>\u7814\u7a76\u8cbb\u540d\uff1a\u79d1\u5b66\u7814\u7a76\u8cbb\uff1a\u57fa\u76e4\u7814\u7a76\uff08B\uff09<br \/>\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a<a href=\"https:\/\/kaken.nii.ac.jp\/grant\/KAKENHI-PROJECT-19H02726\">\u8131\u30ab\u30eb\u30dc\u30cb\u30eb\u578b\u5909\u63db\u53cd\u5fdc\u306e\u975e\u7dda\u5f62\u5c55\u958b\uff1a\u8ee2\u4f4d\u30fb\u8131\u9178\u7d20\u30fb\u30e1\u30bf\u30bb\u30b7\u30b9<\/a><br \/>\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\u3000<a href=\"http:\/\/www.jyamaguchi-lab.com\/\">\u5c71\u53e3\u6f64\u4e00\u90ce\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u30d9\u30f3\u30bc\u30f3\u306a\u3069\u5b89\u4fa1\u306a\u539f\u6599\u304b\u3089\u6709\u7528\u306a\u4e09\u6b21\u5143\u5206\u5b50\u3092\u5408\u6210\u3059\u308b \u89e6\u5a92\u7684\u306a\u8131\u82b3\u9999\u65cf\u7684\u4e8c\u70ad\u7d20\u5b98\u80fd\u57fa\u5316\u53cd\u5fdc\u306e\u958b\u767a\u306b\u6210\u529f \u767a\u8868\u306e\u30dd\u30a4\u30f3\u30c8 \u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u306b\u3088\u308a\u30d9\u30f3\u30bc\u30f3\u74b0\u3092\u58ca\u3057\u306a\u304c\u3089\uff12\u3064\u306e\u70ad\u7d20\u2013\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u306b\u6210\u529f \u69d8\u3005\u306a\u5358\u7d14\u82b3\u9999\u65cf\u5316\u5408\u7269(\u5e73 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":69774,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[40,1],"tags":[357,204,5],"class_list":["post-69772","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-topic","category-news","tag-pressrelease","tag-highlight","tag-research"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/69772","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/comments?post=69772"}],"version-history":[{"count":1,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/69772\/revisions"}],"predecessor-version":[{"id":69780,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/69772\/revisions\/69780"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media\/69774"}],"wp:attachment":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media?parent=69772"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/categories?post=69772"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/tags?post=69772"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}