{"id":69602,"date":"2020-07-09T14:00:55","date_gmt":"2020-07-09T05:00:55","guid":{"rendered":"https:\/\/www.waseda.jp\/top\/?p=69602"},"modified":"2020-07-09T18:30:26","modified_gmt":"2020-07-09T09:30:26","slug":"%e5%b1%b1%e5%8f%a3%e5%85%88%e7%94%9f%e3%83%aa%e3%83%aa%e3%83%bc%e3%82%b9","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/top\/news\/69602","title":{"rendered":"\u30d9\u30f3\u30bc\u30f3\u74b0\u30a8\u30b9\u30c6\u30eb \u89e6\u5a92\u3067\u7570\u6027\u5316\u3059\u308b"},"content":{"rendered":"

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\u8ad6\u6587\u540d\uff1a<\/strong>Ester Dance Reaction on the Aromatic Ring\uff08\u82b3\u9999\u74b0\u4e0a\u306e\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u53cd\u5fdc\uff09<\/a><\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

(4)<\/strong>\u4eca\u56de\u306e\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f\u7d50\u679c\u53ca\u3073\u77e5\u898b<\/strong><\/h3>\n

\u4eca\u56de\u306e\u7814\u7a76\u306b\u3088\u308a\u3001\u533b\u85ac\u54c1\u3084\u6a5f\u80fd\u6027\u5206\u5b50\u3092\u542b\u3081\u305f30\u7a2e\u985e\u4ee5\u4e0a\u306e\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u306b\u304a\u3044\u3066\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u53cd\u5fdc\u304c\u52b9\u7387\u3088\u304f\u9032\u884c\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u672c\u53cd\u5fdc\u3092\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u5f93\u6765\u306e\u624b\u6cd5\u3067\u306f\u5408\u6210\u3059\u308b\u3053\u3068\u304c\u96e3\u3057\u304b\u3063\u305f\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u306e\u8fc5\u901f\u5408\u6210\u306b\u3082\u6210\u529f\u3057\u3066\u3044\u307e\u3059\u3002\u4f8b\u3048\u3070\u3001\u533b\u85ac\u54c1\u30d7\u30ed\u30d9\u30cd\u30b7\u30c9\u3092\u30a8\u30b9\u30c6\u30eb\u5316\u3057\u305f\u5316\u5408\u7269\u306b\u540c\u53cd\u5fdc\u3092\u884c\u3046\u3053\u3068\u3067\u3001C4\u4f4d\u304b\u3089C3\u4f4d\u306b\u79fb\u3059\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u307e\u305f\u5b89\u4fa1\u306a\u30a8\u30b9\u30c6\u30eb\u304b\u3089\u540c\u53cd\u5fdc\u306b\u3088\u308a\u9ad8\u4fa1\u306a\u30a8\u30b9\u30c6\u30eb\u3092\u5408\u6210\u53ef\u80fd\u3067\u3059\u3002\u672c\u53cd\u5fdc\u306b\u3088\u3063\u3066\u5f97\u3089\u308c\u308b\u751f\u6210\u7269\u3082\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u3067\u3042\u308a\u3001\u4e07\u80fd\u5b98\u80fd\u57fa\u3067\u3042\u308b\u30a8\u30b9\u30c6\u30eb\u3092\u3082\u3063\u3066\u3044\u307e\u3059\u3002\u305d\u3053\u3067\u3001\u8fd1\u5e74\u52e2\u529b\u7684\u306b\u7814\u7a76\u3055\u308c\u3066\u3044\u308b\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u3068\u7a2e\u3005\u306e\u6c42\u6838\u5264\uff08\u203b5\uff09<\/strong>\uff08Nu\uff09\u3092\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u5264\u3068\u3057\u305f\u300c\u8131\u30ab\u30eb\u30dc\u30cb\u30eb\u578b\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u300d\u3068\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u3092\u7d44\u307f\u5408\u308f\u305b\u305f\u9010\u6b21\u53cd\u5fdc\u3092\u958b\u767a\u3057\u3001\u69d8\u3005\u306a\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u65b0\u305f\u306a\u5408\u6210\u624b\u6cd5\u3092\u63d0\u4f9b\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u4e00\u90e8\u306e\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u306b\u304a\u3044\u3066\u3001\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u53cd\u5fdc\u3092\u9023\u7d9a\u3057\u3066\u9032\u884c\u3055\u305b\u3066\u30a8\u30b9\u30c6\u30eb\u30921,3-\u8ee2\u4f4d\u3055\u305b\u308b\u3053\u3068\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

(5)<\/strong>\u7814\u7a76\u306e\u6ce2\u53ca\u52b9\u679c\u3084\u793e\u4f1a\u7684\u5f71\u97ff<\/strong><\/h3>\n

\u4eca\u56de\u958b\u767a\u3057\u305f\u300c\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u53cd\u5fdc\u300d\u306f\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u3092\u7528\u3044\u305f\u65b0\u305f\u306a\u89e6\u5a92\u7684\u7570\u6027\u5316\u53cd\u5fdc\u3067\u3059\u3002\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u306f\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3067\u983b\u7528\u3055\u308c\u308b\u57fa\u672c\u69cb\u9020\u306e\u4e00\u3064\u3067\u3042\u308b\u305f\u3081\u3001\u533b\u8fb2\u85ac\u306e\u958b\u767a\u7814\u7a76\u3084\u5de5\u696d\u30d7\u30ed\u30bb\u30b9\u306b\u65b0\u305f\u306a\u624b\u6cd5\u3092\u63d0\u4f9b\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n

\u30a8\u30b9\u30c6\u30eb\u304c\u305d\u306e\u307e\u307e\u3068\u306a\u308a\u306e\u70ad\u7d20\u306b\u79fb\u52d5\u3059\u308b\u3068\u3044\u3046\u30e6\u30cb\u30fc\u30af\u306a\u304c\u3089\u5927\u5909\u30b7\u30f3\u30d7\u30eb\u306a\u624b\u6cd5\u3067\u3042\u308b\u305f\u3081\u3001\u7279\u5225\u306a\u77e5\u8b58\u3092\u6709\u3059\u308b\u5316\u5b66\u8005\u4ee5\u5916\u3067\u3082\u76f4\u622a\u7684\u306b\u7406\u89e3\u3067\u304d\u3001\u8ab0\u3082\u304c\u5229\u7528\u3067\u304d\u308b\u5408\u6210\u30c4\u30fc\u30eb\u306b\u306a\u308a\u5f97\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n

(6)<\/strong>\u4eca\u5f8c\u306e\u8ab2\u984c<\/strong><\/h3>\n

\u65b0\u5f62\u5f0f\u306e\u53cd\u5fdc\u3067\u3042\u308b\u305f\u3081\u9069\u7528\u53ef\u80fd\u306a\u5316\u5408\u7269\u304c\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\u306b\u9650\u3089\u308c\u3066\u3044\u308b\u3053\u3068\u3001\u53cd\u5fdc\u306f\u901a\u5e38\u306e\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u7570\u6027\u5316\u53cd\u5fdc\u306b\u6bd4\u3079\u308b\u3068\u6e29\u548c\u3067\u3059\u304c\u3001\u3044\u307e\u3060\u9ad8\u6e29\uff08150\u2103\uff09\u3092\u5fc5\u8981\u3068\u3059\u308b\u3053\u3068\u304c\u4eca\u5f8c\u306e\u8ab2\u984c\u3067\u3059\u3002\u53cd\u5fdc\u306f\u307e\u3060\u767a\u898b\u3055\u308c\u305f\u3070\u304b\u308a\u3067\u3042\u308b\u305f\u3081\u3001\u4eca\u5f8c\u3001\u69d8\u3005\u306a\u82b3\u9999\u65cf\u5316\u5408\u7269\u3078\u306e\u9069\u7528\u62e1\u5927\u691c\u8a0e\u3084\u3088\u308a\u9ad8\u6d3b\u6027\u306a\u91d1\u5c5e\u89e6\u5a92\u306e\u63a2\u7d22\u3092\u901a\u3058\u3066\u3001\u3053\u308c\u3089\u306e\u8ab2\u984c\u3092\u514b\u670d\u3057\u305f\u3044\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n

(7)<\/strong>\u7528\u8a9e\u89e3\u8aac<\/strong><\/h3>\n

\u203b<\/strong>\uff11\u3000\u82b3\u9999\u65cf\u30a8\u30b9\u30c6\u30eb\uff1a<\/strong>\u30d9\u30f3\u30bc\u30f3\u74b0\u306b\u30a8\u30b9\u30c6\u30eb\uff08COOR\uff09\u304c\u3064\u3044\u305f\u3082\u306e\u3002\u5b89\u4fa1\u306a\u5b89\u606f\u9999\u9178\u8a98\u5c0e\u4f53\u3084\u30b5\u30ea\u30c1\u30eb\u9178\u306a\u3069\u304b\u3089\u8a98\u5c0e\u3067\u304d\u308b\u305f\u3081\u3001\u5bb9\u6613\u306b\u5165\u624b\u53ef\u80fd\u3002\u9999\u308a\u306e\u3042\u308b\u5316\u5408\u7269\u304c\u591a\u3044\u3002<\/p>\n

\u203b2<\/strong>\u3000\u7570\u6027\u5316\u53cd\u5fdc\uff1a<\/strong>\u7f6e\u63db\u57fa\u3092\u5225\u306e\u7d50\u5408\u90e8\u4f4d\uff08\u70ad\u7d20\u306a\u3069\uff09\u306b\u79fb\u3059\u53cd\u5fdc\u306e\u3053\u3068\u3002<\/p>\n

\u203b3 \u00a0<\/strong>\u5b98\u80fd\u57fa\uff1a<\/strong>\u6709\u6a5f\u5316\u5408\u7269\u3067\u53cd\u5fdc\u304c\u9032\u884c\u3057\u3084\u3059\u3044\u90e8\u4f4d\u3002<\/p>\n

\u203b4<\/strong>\u3000\u914d\u4f4d\u5b50\uff1a<\/strong>\u91d1\u5c5e\u89e6\u5a92\u306e\u6027\u8cea\u3092\u5909\u5316\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u90e8\u4f4d\u3002\u3053\u306e\u7cbe\u5bc6\u306a\u8a2d\u8a08\u306b\u3088\u308a\u3001\u89e6\u5a92\u52b9\u7387\u3084\u53cd\u5fdc\u6027\u3092\u5287\u7684\u306b\u5909\u5316\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002<\/p>\n

\u203b5<\/strong>\u3000\u6c42\u6838\u5264\uff1a<\/strong>\u96fb\u5b50\u304c\u4e0d\u8db3\u3057\u3066\u3044\u308b\u5316\u5b66\u7a2e(\u6c42\u96fb\u5b50\u5264)\u3068\u53cd\u5fdc\u3057\u96fb\u5b50\u3092\u53d7\u3051\u6e21\u3059\u3053\u3068\u3067\u5316\u5b66\u7d50\u5408\u3092\u5f62\u6210\u3059\u308b\u5316\u5b66\u7a2e\u3002<\/p>\n

(8)<\/strong>\u8ad6\u6587\u60c5\u5831<\/strong><\/h3>\n

\u63b2\u8f09\u96d1\u8a8c\uff1aScience Advances\uff08\u30b5\u30a4\u30a8\u30f3\u30b9\u30fb\u30a2\u30c9\u30d0\u30f3\u30b7\u30b9\uff09<\/a>
\n<\/strong>\u8ad6\u6587\u540d\uff1a<\/strong>Ester Dance Reaction on the Aromatic Ring\uff08\u82b3\u9999\u74b0\u4e0a\u306e\u30a8\u30b9\u30c6\u30eb\u30c0\u30f3\u30b9\u53cd\u5fdc\uff09<\/a>
\n\u8457\u8005\uff1a<\/strong>Kaoru Matsushita, Ryosuke Takise, Kei Muto<\/a>, and Junichiro Yamaguchi<\/a>\uff08\u677e\u4e0b\u85ab\u3001\u7027\u702c\u77ad\u4ecb\u3001\u6b66\u85e4\u6176<\/a>\u3001\u5c71\u53e3\u6f64\u4e00\u90ce<\/a>\uff09
\n\u8ad6\u6587\u516c\u958b\u65e5\uff1a<\/strong>2020\u5e747\u67088\u65e5 (\u7c73\u56fd\u6771\u90e8\u6a19\u6e96\u6642\uff1a\u590f\u6642\u9593EDT)
\nDOI:<\/strong> 10.1126\/sciadv.aba7614
\n\u63b2\u8f09URL\uff1a <\/strong>https:\/\/doi.org\/10.1126\/sciadv.aba7614<\/a><\/p>\n

(9)<\/strong>\u7814\u7a76\u52a9\u6210<\/strong><\/h3>\n

\u7814\u7a76\u8cbb\u540d\uff1a<\/strong>\u79d1\u5b66\u7814\u7a76\u8cbb \u57fa\u76e4\u7814\u7a76\uff08B\uff09
\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a<\/strong>\u8131\u30ab\u30eb\u30dc\u30cb\u30eb\u578b\u5909\u63db\u53cd\u5fdc\u306e\u975e\u7dda\u5f62\u5c55\u958b\uff1a\u8ee2\u4f4d\u30fb\u8131\u9178\u7d20\u30fb\u30e1\u30bf\u30bb\u30b7\u30b9<\/a>
\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\uff1a<\/strong>\u5c71\u53e3\u6f64\u4e00\u90ce\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n

\u7814\u7a76\u8cbb\u540d\uff1a<\/strong>\u79d1\u5b66\u7814\u7a76\u8cbb \u65b0\u5b66\u8853\u9818\u57df\u7814\u7a76
\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a<\/strong>\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u89e6\u5a92\u7684\u5b98\u80fd\u57fa\u8ee2\u4f4d\u53cd\u5fdc\u306e\u958b\u767a<\/a>
\n\u7814\u7a76\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\uff1a<\/strong>\u5c71\u53e3\u6f64\u4e00\u90ce\uff08\u65e9\u7a32\u7530\u5927\u5b66\uff09<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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