{"id":68826,"date":"2020-03-25T14:00:13","date_gmt":"2020-03-25T05:00:13","guid":{"rendered":"https:\/\/www.waseda.jp\/top\/?p=68826"},"modified":"2020-04-23T10:10:25","modified_gmt":"2020-04-23T01:10:25","slug":"%e3%82%ad%e3%83%a9%e3%83%ab%e3%81%aa%e5%a4%9a%e7%92%b0%e5%bc%8f%e8%8a%b3%e9%a6%99%e6%97%8f%e7%82%ad%e5%8c%96%e6%b0%b4%e7%b4%a0%e3%81%ae%e5%90%88%e6%88%90","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/top\/news\/68826","title":{"rendered":"\u30ad\u30e9\u30eb\u306a\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u5408\u6210"},"content":{"rendered":"<h2><strong>\u512a\u308c\u305f\u767a\u5149\u7279\u6027\u3092\u6709\u3059\u308b\u30ad\u30e9\u30eb\u306a\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u5408\u6210\u306b\u6210\u529f\u3000<\/strong><strong>\u6b21\u4e16\u4ee33D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u7b49\u3078\u306e\u5fdc\u7528\u306b\u671f\u5f85<\/strong><\/h2>\n<h3><strong>\u767a\u8868\u306e\u30dd\u30a4\u30f3\u30c8<\/strong><\/h3>\n<ul>\n<li>\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308b\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u9ad8\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u306b\u6210\u529f\u3057\u305f<\/li>\n<li>\u672c\u6cd5\u306b\u3088\u308a\u5408\u6210\u3055\u308c\u305f\u5206\u5b50\u306f\u512a\u308c\u305f\u767a\u5149\u7279\u6027\u3092\u6709\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f<\/li>\n<li>\u6b21\u4e16\u4ee33D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u3001\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u30fc\u30da\u30a4\u30f3\u30c8\u7b49\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u308b<\/li>\n<\/ul>\n<p>\u65e9\u7a32\u7530\u5927\u5b66\u5927\u5b66\u9662\u5148\u9032\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u535a\u58eb\u5f8c\u671f\u8ab2\u7a0b3\u5e74\u9ad9\u91ce\u79c0\u660e\uff08\u305f\u304b\u306e\u3072\u3067\u3042\u304d\uff09\u6c0f\uff08\u65e5\u672c\u5b66\u8853\u632f\u8208\u4f1a\u7279\u5225\u7814\u7a76\u54e1\uff09\u3001\u540c\u7406\u5de5\u5b66\u8853\u9662\u306e<a href=\"http:\/\/researchers.waseda.jp\/profile\/ja.d533b8f418cab050a32108713c8a0302.html\" target=\"_blank\" rel=\"noopener\">\u67f4\u7530\u9ad8\u7bc4\uff08\u3057\u3070\u305f\u305f\u304b\u306e\u308a\uff09\u6559\u6388<\/a>\u3001\u8fd1\u757f\u5927\u5b66\u5927\u5b66\u9662\u7dcf\u5408\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u306e\u4eca\u4e95\u559c\u80e4\uff08\u3044\u307e\u3044\u3088\u3057\u305f\u306d\uff09\u51c6\u6559\u6388\u3089\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3001\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3<strong>\uff08\u203b\uff11\uff09<\/strong>\u3092\u6709\u3059\u308b\u70ad\u7d20\u3001\u6c34\u7d20\u306e\u307f\u304b\u3089\u306a\u308b\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20(polycyclic aromatic hydrocarbons: \u7565\u3057\u3066PAHs)\u306e\u9ad8\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210<strong>\uff08\u203b\uff12\uff09<\/strong>\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u672c\u6cd5\u306b\u3088\u308a\u5408\u6210\u3055\u308c\u305f\u5206\u5b50\u306f\u512a\u308c\u305f\u767a\u5149\u7279\u6027\u3092\u6709\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u8fd1\u5e74\u3001PAHs\u306f\u6709\u6a5f\u96fb\u5b50\u6750\u6599\u3078\u5fdc\u7528\u3055\u308c\u308b\u306a\u3069\u3001\u6b21\u4e16\u4ee3\u306e\u6709\u6a5f\u5206\u5b50\u3068\u3057\u3066\u7cbe\u529b\u7684\u306b\u7814\u7a76\u304c\u884c\u308f\u308c\u3066\u3044\u307e\u3059\u3002\u7279\u306b\u30ad\u30e9\u30eb<strong>\uff08\u203b\uff13\uff09<\/strong>\u306aPAHs\u306f\u7279\u7570\u306a\u5149\u5b66\u7279\u6027\u3067\u3042\u308b\u5186\u504f\u5149\u767a\u5149\uff08circularly polarized luminescence: CPL\uff09\u7279\u6027<strong>\uff08\u203b\uff14\uff09<\/strong>\u3092\u6709\u3059\u308b\u5834\u5408\u304c\u3042\u308a\u3001\u6b21\u4e16\u4ee3\u306e3D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u306a\u3069\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u4eca\u56de\u3001\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u304c\u958b\u767a\u3057\u305f\u624b\u6cd5\u306f\u3001\u65b0\u898f\u306a\u6709\u6a5f\u53cd\u5fdc\u3078\u306e\u5c55\u958b\u304c\u671f\u5f85\u3067\u304d\u308b\u307b\u304b\u3001\u30ad\u30e9\u30ebPAHs\u306e\u7814\u7a76\u306b\u3055\u3089\u306a\u308b\u767a\u5c55\u3092\u3082\u305f\u3089\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u52a0\u3048\u3066\u3001\u5f97\u3089\u308c\u305f\u5206\u5b50\u306f\u6bd4\u8f03\u7684\u512a\u308c\u305f\u5149\u5b66\u7279\u6027\u3092\u6709\u3057\u3066\u3044\u305f\u3053\u3068\u304b\u3089\u3001\u4eca\u5f8c\u3001CPL\u7279\u6027\u3092\u6d3b\u7528\u3057\u305f3D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u3001\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u30fc\u30da\u30a4\u30f3\u30c8\u7b49\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n<p>\u672c\u7814\u7a76\u6210\u679c\u306f\u3001\u30a2\u30e1\u30ea\u30ab\u5316\u5b66\u4f1a\u767a\u884c\u306e\u300e<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b12205\">Journal of the American Chemical Society<\/a>\u300f\u306e\u30aa\u30f3\u30e9\u30a4\u30f3\u7248\u306b\uff12\uff10\uff12\uff10\u5e74\uff12\u6708\uff11\uff12\u65e5\u306b\u63b2\u8f09\u3055\u308c\u3001\uff13\u6708\uff11\uff11\u65e5\u306b\u8a8c\u9762\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002\u307e\u305f\u3001<a href=\"https:\/\/pubs.acs.org\/toc\/jacsat\/current\">4\u670822\u65e5\u53f7\u306e\u8868\u7d19\u306b\u63a1\u7528\u3055\u308c\u307e\u3057\u305f\u3002<\/a><\/p>\n<p><a href=\"https:\/\/pubs.acs.org\/pb-assets\/images\/_journalCovers\/jacsat\/jacsat_v142i016.jpg?0.03265479045825659\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-69084\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/shibata-takanori-610x852.jpg\" alt=\"\" width=\"287\" height=\"400\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4><strong>(1)<\/strong><strong>\u3053\u308c\u307e\u3067\u306e\u7814\u7a76\u3067\u5206\u304b\u3063\u3066\u3044\u305f\u3053\u3068<\/strong><\/h4>\n<p>\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20(polycyclic aromatic hydrocarbons: \u7565\u3057\u3066PAHs)\u306f\u30d9\u30f3\u30bc\u30f3\u74b0\u304c\u9ad8\u5ea6\u306b\u9023\u7d50\u3057\u305f\u70ad\u7d20\u3001\u6c34\u7d20\u306e\u307f\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u5316\u5408\u7269\u3067\u3059\u3002\u8fd1\u5e74\u3001PAHs\u306f\u6709\u6a5f\u96fb\u5b50\u6750\u6599\u3078\u5fdc\u7528\u3055\u308c\u308b\u306a\u3069\u3001\u6b21\u4e16\u4ee3\u306e\u6709\u6a5f\u5206\u5b50\u3068\u3057\u3066\u7cbe\u529b\u7684\u306b\u7814\u7a76\u304c\u884c\u308f\u308c\u3066\u3044\u307e\u3059\u3002\u7279\u306b\u30ad\u30e9\u30eb\u306aPAHs\u306f\u7279\u7570\u306a\u5149\u5b66\u7279\u6027\u3067\u3042\u308b\u5186\u504f\u5149\u767a\u5149\uff08circularly polarized luminescence: CPL\uff09\u7279\u6027\u3092\u6709\u3059\u308b\u5834\u5408\u304c\u3042\u308a\u3001\u6b21\u4e16\u4ee3\u306e3D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u306a\u3069\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u4e00\u65b9\u4e00\u822c\u7684\u306b\u30ad\u30e9\u30eb\u306aPAHs\u3092\u5f97\u308b\u305f\u3081\u306b\u306f\u3001\u53f3\u624b\u578b\u5206\u5b50\u3068\u5de6\u624b\u578b\u5206\u5b50\u304c1:1\u3067\u6df7\u5408\u3057\u305f\u30e9\u30bb\u30df\u4f53\u3092\u5408\u6210\u3057\u3001\u30ad\u30e9\u30eb\u306a\u30ab\u30e9\u30e0\u3092\u7528\u3044\u3066\u305d\u308c\u3089\u3092\u5206\u96e2(\u5149\u5b66\u5206\u5272)\u3059\u308b\u3053\u3068\u304c\u5fc5\u8981\u3067\u3057\u305f\u3002\u3088\u308a\u52b9\u7387\u7684\u306a\u5408\u6210\u65b9\u6cd5\u3068\u3057\u3066\u3001\u30ad\u30e9\u30eb\u306a\u89e6\u5a92\u3092\u7528\u3044\u3066\u3001\u89e6\u5a92\u7684\u306b\u30ad\u30e9\u30ebPAHs\u3092\u5f97\u308b\u624b\u6cd5\u3082\u73fe\u5728\u307e\u3067\u306b\u958b\u767a\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u3057\u304b\u3057\u306a\u304c\u3089\u3001\u305d\u306e\u624b\u6cd5\u306f\u3089\u305b\u3093\u69cb\u9020\u306b\u7531\u6765\u3059\u308b\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6301\u3064PAHs\u306b\u306e\u307f\u9650\u3089\u308c\u3066\u304a\u308a\u3001\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308bPAHs\u306e\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u306e\u5831\u544a\u306f\u3042\u308a\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n<h4><strong>(2)<\/strong><strong>\u4eca\u56de\u306e\u7814\u7a76\u3067\u65b0\u305f\u306b\u5b9f\u73fe\u3057\u3088\u3046\u3068\u3057\u305f\u3053\u3068\u3001\u660e\u3089\u304b\u306b\u306a\u3063\u305f\u3053\u3068<\/strong><\/h4>\n<div id=\"attachment_68857\" class=\"wp-caption alignright\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-68857\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_pic-610x424.jpg\" alt=\"\" width=\"350\" height=\"243\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_pic-610x424.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_pic-768x534.jpg 768w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_pic-2000x1390.jpg 2000w\" sizes=\"auto, (max-width: 350px) 100vw, 350px\" \/><p class=\"wp-caption-text\">\u5de6\u304b\u3089\u67f4\u7530\u9ad8\u7bc4\u6559\u6388\u3001\u5869\u6fa4\u590f\u6d77\u6c0f\u3001\u9ad9\u91ce\u79c0\u660e\u6c0f<\/p><\/div>\n<p>\u65e9\u7a32\u7530\u5927\u5b66\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7 (\u5927\u5b66\u9662\u5148\u9032\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u535a\u58eb\u5f8c\u671f\u8ab2\u7a0b3\u5e74\u9ad9\u91ce\u79c0\u660e\uff08\u65e5\u672c\u5b66\u8853\u632f\u8208\u4f1a\u7279\u5225\u7814\u7a76\u54e1\uff09\u3001\u540c\u4fee\u58eb\u8ab2\u7a0b1\u5e74\u5869\u6fa4\u590f\u6d77\u3001\u7406\u5de5\u5b66\u8853\u9662<a href=\"http:\/\/researchers.waseda.jp\/profile\/ja.b0f487fa30c9b8c28d973db970bb041d.html\" target=\"_blank\" rel=\"noopener\">Kyalo Stephen Kanyiva\u51c6\u6559\u6388<\/a>\u3001\u540c<a href=\"http:\/\/researchers.waseda.jp\/profile\/ja.d533b8f418cab050a32108713c8a0302.html\" target=\"_blank\" rel=\"noopener\">\u67f4\u7530\u9ad8\u7bc4\u6559\u6388<\/a>)\u3068\u8fd1\u757f\u5927\u5b66\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7(\u5927\u5b66\u9662\u7dcf\u5408\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u4eca\u4e95\u559c\u80e4\u51c6\u6559\u6388)\u306f\u3001\u3075\u305f\u3064\u306e\u30d9\u30f3\u30bc\u30f3\u74b0\u304b\u3089\u306a\u308b\u30d3\u30d5\u30a7\u30cb\u30ec\u30f3\u3068\u30a2\u30eb\u30ad\u30f3\u90e8\u4f4d\u304c\u9023\u7d50\u3057\u305f\u5316\u5408\u7269\u304b\u3089\u3001\u30ad\u30e9\u30eb\u9077\u79fb\u91d1\u5c5e\u89e6\u5a92\u3092\u7528\u3044\u3066\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308bPAHs\u306e\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u306b\u6311\u307f\u307e\u3057\u305f\u3002<\/p>\n<h4><strong>(3)<\/strong><strong>\u305d\u306e\u305f\u3081\u306b\u65b0\u3057\u304f\u958b\u767a\u3057\u305f\u624b\u6cd5<\/strong><\/h4>\n<p>\u4eca\u56de\u7528\u3044\u305f\u30d3\u30d5\u30a7\u30cb\u30ec\u30f3\u306f\u3001\u4e2d\u592e\u306e\u56db\u54e1\u74b0\u90e8\u5206\u306b\u5927\u304d\u306a\u6b6a\u307f\u3092\u6709\u3057\u3066\u304a\u308a\u3001\u9077\u79fb\u91d1\u5c5e\u89e6\u5a92\u306b\u3088\u3063\u3066\u5bb9\u6613\u306b\u305d\u306e\u70ad\u7d20\u2015\u70ad\u7d20\u7d50\u5408\u3092\u5207\u65ad\u3067\u304d\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u3057\u304b\u3057\u306a\u304c\u3089\u3001\u7f6e\u63db\u57fa\u3092\u6301\u3064\u30d3\u30d5\u30a7\u30cb\u30ec\u30f3\u306e\u5834\u5408\u3001\u7f6e\u63db\u57fa\u3068\u306e\u7acb\u4f53\u7684\u306a\u53cd\u767a\u3092\u907f\u3051\u3001\u7f6e\u63db\u57fa\u306e\u306a\u3044\u7a7a\u3044\u305f\u70ad\u7d20\u2015\u70ad\u7d20\u7d50\u5408\u304c\u9078\u629e\u7684\u306b\u5207\u65ad\u3092\u53d7\u3051\u307e\u3059\u3002\u305d\u3053\u3067\u672c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3001\u7f6e\u63db\u57fa\u90e8\u4f4d\u306b\u91d1\u5c5e\u3068\u76f8\u4e92\u4f5c\u7528\u3059\u308b\u30a2\u30eb\u30ad\u30f3\u90e8\u4f4d\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u3067\u3001\u7acb\u4f53\u7684\u306b\u6df7\u307f\u5408\u3063\u305f\u70ad\u7d20\u2015\u70ad\u7d20\u7d50\u5408\u3078\u89e6\u5a92\u3092\u63a5\u8fd1\u3055\u305b\u3001\u76ee\u7684\u306e\u70ad\u7d20\u2015\u70ad\u7d20\u7d50\u5408\u3092\u9078\u629e\u7684\u306b\u5207\u65ad\u3059\u308b\u624b\u6cd5\u3092\u958b\u767a\u3057\u307e\u3057\u305f\u3002\u30a2\u30eb\u30ad\u30f3\u90e8\u4f4d\u306f\u91d1\u5c5e\u3092\u76ee\u7684\u306e\u5834\u6240\u306b\u63a5\u8fd1\u3055\u305b\u308b\u300c\u914d\u5411\u57fa\u300d\u306e\u5f79\u5272\u3060\u3051\u3067\u306a\u304f\u3001\u91d1\u5c5e\u89e6\u5a92\u3068\u53cd\u5fdc\u3057\u65b0\u305f\u306a\u82b3\u9999\u65cf\u5316\u5408\u7269\u3078\u5909\u63db\u3059\u308b\u305f\u3081\u306e\u300c\u53cd\u5fdc\u90e8\u4f4d\u300d\u3068\u3057\u3066\u306e\u5f79\u5272\u3082\u3042\u308a\u307e\u3059\u3002\u305d\u308c\u306b\u3088\u308a\u3001\uff14\u3064\u306e\u30d9\u30f3\u30bc\u30f3\u74b0\u3067\u69cb\u7bc9\u3055\u308c\u308b\u30d9\u30f3\u30be\u30d5\u30eb\u30aa\u30e9\u30f3\u30c6\u30f3\u8a98\u5c0e\u4f53\u3092\u5f97\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u307e\u305f\u30a2\u30eb\u30ad\u30f3\u90e8\u4f4d\u306b\u7f6e\u63db\u57fa\u3092\u6301\u3064\u30d9\u30f3\u30bc\u30f3\u74b0\u3092\u5c0e\u5165\u3057\u3001\u305d\u306e\u7f6e\u63db\u57fa\u3068\u30d9\u30f3\u30be\u30d5\u30eb\u30aa\u30e9\u30f3\u30c6\u30f3\u9aa8\u683c\u3068\u306e\u7acb\u4f53\u53cd\u767a\u306b\u3088\u308a\u3001\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u69cb\u7bc9\u3057\u307e\u3057\u305f\u3002\u30ad\u30e9\u30eb\u30ed\u30b8\u30a6\u30e0\u89e6\u5a92\u3092\u7528\u3044\u308b\u53cd\u5fdc\u306b\u3088\u308a\u3001\u975e\u5e38\u306b\u9ad8\u3044\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u6027\u304b\u3064\u975e\u5e38\u306b\u9ad8\u3044\u53ce\u7387\u3067\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308bPAHs\u306e\u5408\u6210\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u53cd\u5fdc\u90e8\u4f4d\u3092\uff12\u3064\u6709\u3059\u308b\u5316\u5408\u7269\u3092\u7528\u3044\u308b\u3053\u3068\u3067\uff17\u3064\u306e\u30d9\u30f3\u30bc\u30f3\u74b0\u304b\u3089\u306a\u308b\u30ad\u30e9\u30ebPAHs\u306e\u52b9\u7387\u5408\u6210\u3082\u9054\u6210\u3057\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u5f97\u3089\u308c\u305fPAH\u306e\u4e00\u3064\u306f\u3001\u5c0f\u5206\u5b50\u3068\u3057\u3066\u6bd4\u8f03\u7684\u512a\u308c\u305fCPL\u7279\u6027\u3092\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-68832 aligncenter\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme1-610x192.jpg\" alt=\"\" width=\"500\" height=\"157\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme1-610x192.jpg 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme1-768x242.jpg 768w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme1.jpg 1275w\" sizes=\"auto, (max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-68833 aligncenter\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme2-610x497.png\" alt=\"\" width=\"550\" height=\"448\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme2-610x497.png 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme2.png 688w\" sizes=\"auto, (max-width: 550px) 100vw, 550px\" \/><\/p>\n<h4><strong>(4)<\/strong><strong>\u7814\u7a76\u306e\u6ce2\u53ca\u52b9\u679c\u3084\u793e\u4f1a\u7684\u5f71\u97ff<\/strong><\/h4>\n<p>\u4eca\u56de\u7528\u3044\u305f\u3001\u30a2\u30eb\u30ad\u30f3\u90e8\u4f4d\u3092\u300c\u914d\u5411\u57fa\u300d\u304b\u3064\u300c\u53cd\u5fdc\u90e8\u4f4d\u300d\u3068\u3057\u3066\u7528\u3044\u308b\u624b\u6cd5\u306f\u3001\u7121\u99c4\u306a\u7f6e\u63db\u57fa\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u306a\u304f\u76ee\u7684\u5316\u5408\u7269\u3092\u5408\u6210\u3059\u308b\u624b\u6cd5\u3068\u3057\u3066\u3001\u65b0\u898f\u306a\u6709\u6a5f\u53cd\u5fdc\u3078\u306e\u5c55\u958b\u304c\u671f\u5f85\u3067\u304d\u307e\u3059\u3002\u307e\u305f\u3001\u4eca\u56de\u958b\u767a\u3057\u305f\u53cd\u5fdc\u306f\u3001\u53f3\u624b\u578b\u5206\u5b50\u3068\u5de6\u624b\u578b\u5206\u5b50\u306e\u3046\u3061\u306e\u4e00\u65b9\u306e\u307f\u3092\u9078\u629e\u7684\u306b\u5f97\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u624b\u6cd5\u3067\u3042\u308b\u305f\u3081\u3001\u30ad\u30e9\u30ebPAHs\u306e\u7814\u7a76\u306b\u3055\u3089\u306a\u308b\u767a\u5c55\u3092\u3082\u305f\u3089\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u52a0\u3048\u3066\u3001\u5f97\u3089\u308c\u305f\u5206\u5b50\u306f\u6bd4\u8f03\u7684\u512a\u308c\u305f\u5149\u5b66\u7279\u6027\u3092\u6709\u3057\u3066\u3044\u305f\u3053\u3068\u304b\u3089\u3001\u4eca\u5f8c\u3001\u3055\u3089\u306a\u308b\u5206\u5b50\u30c7\u30b6\u30a4\u30f3\u306b\u3088\u308a\u3001CPL\u7279\u6027\u3092\u6d3b\u7528\u3057\u305f\u6280\u8853(3D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u3001\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u30fc\u30da\u30a4\u30f3\u30c8\u7b49)\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n<h4><strong>(5)<\/strong><strong>\u4eca\u5f8c\u306e\u8ab2\u984c<\/strong><\/h4>\n<p>\u73fe\u6642\u70b9\u3067\u306e\u6700\u9069\u306a\u6761\u4ef6\u306f\u3001\u53cd\u5fdc\u6e29\u5ea6\u304c80\u5ea6\u3067\u3001\u53cd\u5fdc\u6642\u9593\u304c24\u6642\u9593\u3067\u3059\u3002\u4eca\u5f8c\u3001\u3088\u308a\u6e29\u548c\u306a\u6761\u4ef6\u3001\u4f8b\u3048\u3070\u3001\u5ba4\u6e29\u30671\u6642\u9593\u4ee5\u5185\u306b\u53cd\u5fdc\u304c\u5b8c\u7d50\u3059\u308b\u89e6\u5a92\u7cfb\u306e\u63a2\u7d22\u3092\u884c\u3044\u307e\u3059\u3002\u307e\u305f\u3001\u4eca\u56de\u5408\u6210\u3057\u305f\u30ad\u30e9\u30ebPAHs\u306b\u306f\u30d9\u30f3\u30be\u30d5\u30eb\u30aa\u30e9\u30f3\u30c6\u30f3\u9aa8\u683c\u304c\u5fc5\u305a\u542b\u307e\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u3055\u3089\u306a\u308b\u57fa\u8cea\u306e\u30c7\u30b6\u30a4\u30f3\u306b\u3088\u308a\u3001\u591a\u69d8\u306a\u69cb\u9020\u306e\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308bPAHs\u3092\u5408\u6210\u3057\u3001\u3088\u308a\u5149\u5b66\u7279\u6027\u306e\u512a\u308c\u305f\u5316\u5408\u7269\u306e\u5275\u88fd\u3092\u76ee\u6307\u3057\u307e\u3059\u3002<\/p>\n<h4><strong>(6)<\/strong><strong>\u7528\u8a9e\u89e3\u8aac<\/strong><\/h4>\n<ul>\n<li><strong>\u203b1\u3000<\/strong><strong>\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3<\/strong><\/li>\n<\/ul>\n<p>\u3042\u308b\u5316\u5408\u7269\u306e\u5358\u7d50\u5408\uff08\u8ef8\uff09\u304c\u7f6e\u63db\u57fa\u306e\u7acb\u4f53\u53cd\u767a\u306b\u3088\u308a\u56de\u8ee2\u304c\u3067\u304d\u306a\u3044\u3053\u3068\u306a\u3069\u306b\u7531\u6765\u3057\u3001\u305d\u306e\u93e1\u50cf\u4f53\u3068\u91cd\u306d\u308b\u3053\u3068\u304c\u3067\u304d\u306a\u3044\u3053\u3068\u3092\u3001\u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3068\u3088\u3076\u3002 (\u4e0b\u56f3\u53c2\u7167)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-68836\" src=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme3-610x498.png\" alt=\"\" width=\"350\" height=\"285\" srcset=\"https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme3-610x498.png 610w, https:\/\/www.waseda.jp\/top\/assets\/uploads\/2020\/03\/20200325_Scheme3.png 705w\" sizes=\"auto, (max-width: 350px) 100vw, 350px\" \/><\/p>\n<ul>\n<li><strong>\u203b\uff12\u3000\u9ad8\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210<\/strong><\/li>\n<\/ul>\n<p>\u30ad\u30e9\u30eb\u306a\u5316\u5408\u7269\u306b\u304a\u3044\u3066\u3001\u93e1\u50cf\u95a2\u4fc2\u306b\u3042\u308b\u53f3\u624b\u578b\u5206\u5b50\u3068\u5de6\u624b\u578b\u5206\u5b50\u306e\u3046\u3061\u306e\u4e00\u65b9\u3092\u9078\u629e\u7684\u306b\u4f5c\u308b\u3053\u3068\u3002<\/p>\n<ul>\n<li><strong>\u203b\uff13\u3000\u30ad\u30e9\u30eb<\/strong><\/li>\n<\/ul>\n<p>\u3042\u308b\u73fe\u8c61\u306e\u93e1\u50cf\u4f53\u304c\u3001\u5143\u3005\u306e\u73fe\u8c61\u3068\u91cd\u306d\u308b\u3053\u3068\u304c\u3067\u304d\u306a\u3044\u6027\u8cea\u306e\u3053\u3068\u3092\u6307\u3059\u3002<\/p>\n<ul>\n<li><strong>\u203b\uff14\u3000\u5186\u504f\u5149\u767a\u5149(CPL)\u7279\u6027<\/strong><\/li>\n<\/ul>\n<p>\u5149\u306f\u5782\u76f4\u306a\u9762\u5185\u3067\u632f\u52d5\u3059\u308b\u6ce2\u3067\u3042\u308b\u304c\u3001\u305d\u306e\u632f\u52d5\u9762\u304c\u3089\u305b\u3093\u72b6\u306b\u56de\u8ee2\u3057\u306a\u304c\u3089\u9032\u3080\u5149\u306e\u3053\u3068\u3092\u5186\u504f\u5149\u3068\u3044\u3044\u3001\u5186\u504f\u5149\u3092\u767a\u5149\u3059\u308b\u6027\u8cea\u3092\u5186\u504f\u5149\u767a\u5149\u7279\u6027\u3068\u3044\u3046\u3002<\/p>\n<h4><strong>(7)<\/strong><strong>\u8ad6\u6587\u60c5\u5831<\/strong><\/h4>\n<ul>\n<li><strong>\u96d1\u8a8c\u540d\uff1a<\/strong>Journal of the American Chemical Society<\/li>\n<li><strong>\u8ad6\u6587\u540d\uff1a<\/strong>Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C\u2013C Bond Activation of Biphenylenes<\/li>\n<li><strong>\u57f7\u7b46\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\uff1a<\/strong>Hideaki Takano (Waseda University), Natsumi Shiozawa (Waseda University), Yoshitane Imai (Kindai University), Kyalo Stephen Kanyiva (Waseda University), Takanori Shibata (Waseda University)<\/li>\n<li><strong>\u8a8c\u9762\u63b2\u8f09\u65e5\u6642\uff08\u73fe\u5730\u6642\u9593\uff09<\/strong>\uff1a\uff12\uff10\uff12\uff10\u5e74\uff13\u6708\uff11\uff11\u65e5<\/li>\n<li><strong>\u30aa\u30f3\u30e9\u30a4\u30f3\u63b2\u8f09\u65e5\u6642\uff08\u73fe\u5730\u6642\u9593\uff09\uff1a<\/strong>\uff12\uff10\uff12\uff10\u5e74\uff12\u6708\uff11\uff12\u65e5<\/li>\n<li><strong>\u63b2\u8f09URL\uff1a<\/strong><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b12205\" target=\"_blank\" rel=\"noopener\">https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b12205<\/a><\/li>\n<li><strong>DOI<\/strong><strong>\uff1a<\/strong>10.1021\/jacs.9b12205<\/li>\n<\/ul>\n<h4><strong>(8)<\/strong><strong>\u7814\u7a76\u52a9\u6210<\/strong><\/h4>\n<ul>\n<li><strong>\u7814\u7a76\u8cbb\u540d\uff1a<\/strong>\u79d1\u5b66\u7814\u7a76\u8cbb\u52a9\u6210\u4e8b\u696d\u3000\u7279\u5225\u7814\u7a76\u54e1\u5968\u52b1\u8cbb<\/li>\n<li><strong>\u7814\u7a76\u8ab2\u984c\u540d\uff1a<\/strong>\u89e6\u5a92\u7684\u4e0d\u6589\u70ad\u7d20\u30fc\u70ad\u7d20\u7d50\u5408\u6d3b\u6027\u5316\u53cd\u5fdc\u3092\u5229\u7528\u3057\u305f\u6b6a\u3093\u3060\u7e2e\u5408\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u5316\u5408\u7269\u306e\u5275\u88fd<\/li>\n<li><strong>\u7814\u7a76\u4ee3\u8868\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\uff1a<\/strong>\u9ad9\u91ce\u79c0\u660e (\u65e9\u7a32\u7530\u5927\u5b66\u5927\u5b66\u9662\u5148\u9032\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u3001\u65e5\u672c\u5b66\u8853\u632f\u8208\u4f1a\u7279\u5225\u7814\u7a76\u54e1(DC2))<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u512a\u308c\u305f\u767a\u5149\u7279\u6027\u3092\u6709\u3059\u308b\u30ad\u30e9\u30eb\u306a\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u5408\u6210\u306b\u6210\u529f\u3000\u6b21\u4e16\u4ee33D\u30c7\u30a3\u30b9\u30d7\u30ec\u30a4\u7b49\u3078\u306e\u5fdc\u7528\u306b\u671f\u5f85 \u767a\u8868\u306e\u30dd\u30a4\u30f3\u30c8 \u8ef8\u6027\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308b\u591a\u74b0\u5f0f\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u9ad8\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u306b\u6210\u529f\u3057\u305f \u672c\u6cd5\u306b\u3088\u308a\u5408\u6210\u3055\u308c\u305f\u5206 [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":68838,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[40,1],"tags":[357,204,5],"class_list":["post-68826","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-topic","category-news","tag-pressrelease","tag-highlight","tag-research"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/68826","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/comments?post=68826"}],"version-history":[{"count":2,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/68826\/revisions"}],"predecessor-version":[{"id":69083,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/posts\/68826\/revisions\/69083"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media\/68838"}],"wp:attachment":[{"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/media?parent=68826"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/categories?post=68826"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.waseda.jp\/top\/wp-json\/wp\/v2\/tags?post=68826"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}