{"id":80663,"date":"2025-03-15T13:53:21","date_gmt":"2025-03-15T04:53:21","guid":{"rendered":"https:\/\/www.waseda.jp\/inst\/research\/?p=80663"},"modified":"2025-04-15T13:53:32","modified_gmt":"2025-04-15T04:53:32","slug":"oxidative-dehydrogenation-of-ethane-combined-with-co2-splitting-via-chemical%ef%bc%88published-in-acs-catalysis-march-2025%ef%bc%89","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/inst\/research\/news\/80663","title":{"rendered":"Oxidative Dehydrogenation of Ethane Combined with CO2 Splitting via Chemical\uff08Published in ACS Catalysis, March, 2025\uff09"},"content":{"rendered":"<table class=\"table table-bordered table-colored-tbhd\" style=\"height: 550px; width: 100%; border-collapse: collapse; border-style: solid;\" border=\"1\">\n<tbody>\n<tr style=\"height: 78px;\">\n<td style=\"width: 19.0523%; height: 78px;\">Journal Title<br \/>\n\/\u63b2\u8f09\u30b8\u30e3\u30fc\u30ca\u30eb\u540d<\/td>\n<td style=\"width: 80.849%; height: 78px;\">ACS Catalysis<\/td>\n<\/tr>\n<tr style=\"height: 65px;\">\n<td style=\"width: 19.0523%; height: 80px;\">Publication Year and Month<br \/>\n\/\u63b2\u8f09\u5e74\u6708<\/td>\n<td style=\"width: 80.849%; height: 80px;\">March, 2025<\/td>\n<\/tr>\n<tr style=\"height: 55px;\">\n<td style=\"width: 19.0523%; height: 79px;\">Paper Title<br \/>\n\/\u8ad6\u6587\u30bf\u30a4\u30c8\u30eb<\/td>\n<td style=\"width: 80.849%; height: 79px;\">Oxidative Dehydrogenation of Ethane Combined with CO2 Splitting via Chemical<\/td>\n<\/tr>\n<tr style=\"height: 85px;\">\n<td style=\"width: 19.0523%; height: 85px;\">DOI<br \/>\n\/\u8ad6\u6587DOI<\/td>\n<td style=\"width: 80.849%; height: 85px;\"><a href=\"https:\/\/doi.org\/10.1021\/acscatal.4c07737\">10.1021\/acscatal.4c07737<\/a><\/td>\n<\/tr>\n<tr style=\"height: 59px;\">\n<td style=\"width: 19.0523%; height: 80px;\">\u00a0Author of Waseda University<br \/>\n\/\u672c\u5b66\u306e\u8457\u8005<\/td>\n<td style=\"width: 80.849%; height: 80px;\"><span style=\"font-family: inherit; font-size: inherit;\">SEKINE, Yasushi(Professor, Faculty of Science and Engineering, School of Advanced Science and Engineering):Correspoinding Author<\/span><\/td>\n<\/tr>\n<tr style=\"height: 68px;\">\n<td style=\"width: 19.0523%; height: 86px;\">Related Websites<br \/>\n\/\u95a2\u9023Web<\/td>\n<td style=\"width: 80.849%; height: 86px;\">&#8211;<\/td>\n<\/tr>\n<tr style=\"height: 138px;\">\n<td style=\"width: 19.0523%; height: 148px;\">Abstract<br \/>\n\/\u6284\u9332<\/td>\n<td style=\"width: 80.849%; height: 148px;\">Modified In<sub>2<\/sub>O<sub>3<\/sub>\u00a0has the potential to be a better oxygen storage material due to its readily reducible surface and abundant bulk lattice oxygen released with a marked valence change from In<sup>3+<\/sup>\u00a0to In<sup>0<\/sup>. This work describes that In<sub>2<\/sub>O<sub>3<\/sub>\u00a0modified with a Ni\u2013Cu alloy supports a chemical looping system consisting of oxidative dehydrogenation of ethane and CO<sub>2<\/sub>\u00a0splitting at the low temperature of 873 K with a large oxygen capacity (&gt;4 wt %). This reaction system is achieved through dynamic changes between Ni\u2013Cu binary alloy and Ni\u2013Cu\u2013In ternary alloy associated with the redox of indium species. Meticulous material screening, characterization, and theoretical calculations have revealed that the Ni\u2013Cu alloy promotes the redox of In<sub>2<\/sub>O<sub>3<\/sub>\u00a0by activating ethane and by incorporating reduced indium species.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"<p>Journal Title \/\u63b2\u8f09\u30b8\u30e3\u30fc\u30ca\u30eb\u540d ACS Catalysis Publication Year and Month \/\u63b2\u8f09\u5e74\u6708 March, 2025 Paper Title \/\u8ad6\u6587\u30bf\u30a4\u30c8\u30eb Oxidati [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[],"tags":[218,217],"class_list":["post-80663","post","type-post","status-publish","format-standard","hentry","tag-impact-en","tag-impact"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/80663","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/comments?post=80663"}],"version-history":[{"count":1,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/80663\/revisions"}],"predecessor-version":[{"id":80664,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/80663\/revisions\/80664"}],"wp:attachment":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/media?parent=80663"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/categories?post=80663"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/tags?post=80663"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}