{"id":79861,"date":"2025-03-07T14:00:25","date_gmt":"2025-03-07T05:00:25","guid":{"rendered":"https:\/\/www.waseda.jp\/inst\/research\/?p=79861"},"modified":"2025-03-07T13:09:51","modified_gmt":"2025-03-07T04:09:51","slug":"%e7%b7%a8%e9%9b%86%e4%b8%ad-7","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/inst\/research\/news\/79861","title":{"rendered":"\u4e00\u6b21\u5143\u3089\u305b\u3093\u69cb\u9020\u306e\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u7d50\u6676\u3067\u5de8\u5927\u306a\u5149\u8d77\u96fb\u529b\u3092\u5b9f\u8a3c"},"content":{"rendered":"<h2 style=\"text-align: center;\">\u4e00\u6b21\u5143\u3089\u305b\u3093\u69cb\u9020\u306e\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u7d50\u6676\u3067\u5de8\u5927\u306a\u5149\u8d77\u96fb\u529b\u3092\u5b9f\u8a3c<\/h2>\n<p style=\"text-align: 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V\u3092\u8d85\u3048\u308b\u5de8\u5927\u306a\u5149\u8d77\u96fb\u529b\u3092\u767a\u73fe\u3055\u305b\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002<br 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Chemie International Edition\u300f\u306b2025\u5e743\u67083\u65e5\uff08\u6708\uff09\uff08\u73fe\u5730\u6642\u9593\uff09\u306b\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<div id=\"attachment_79947\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-79947 size-full\" src=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/da9c8fe340571bb3c3001d536a63234d.png\" alt=\"\" width=\"835\" height=\"339\" srcset=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/da9c8fe340571bb3c3001d536a63234d.png 835w, https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/da9c8fe340571bb3c3001d536a63234d-610x248.png 610w, https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/da9c8fe340571bb3c3001d536a63234d-768x312.png 768w\" sizes=\"auto, (max-width: 835px) 100vw, 835px\" \/><p 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Ishii, T. Miyasaka, Science Adv., 2020, 6, eabd3274\uff09\u3002\u305f\u3068\u3048\u3070\u3001PbI\u2082\u306f\u3001R-(+)\u304a\u3088\u3073S-(\u2012)-(1-\u30ca\u30d5\u30c1\u30eb)\u30a8\u30c1\u30eb\u30a2\u30df\u30f3\uff08R (S)-1-NEA\u207a\uff09\u3068\u306e\u30e8\u30a6\u7d20\u3092\u4ecb\u3057\u305f\u6c34\u7d20\u7d50\u5408\u306b\u3088\u308a\u3001[PbI\u2086]\u2074\u207b\u304b\u3089\u306a\u308b\u516b\u9762\u4f53\u69cb\u9020\u304c\u9762\u3092\u5171\u6709\u3057\u9023\u7d50\u3057\u305f\u4e00\u6b21\u5143\u3089\u305b\u3093\u69cb\u9020\uff08(R (S)-1-NEA)PbI\u2083\uff09\u3092\u5f62\u6210\u3057\u307e\u3059\uff08\u56f31\uff09\u3002\u3053\u306e\u7d50\u6676\u306e\u7a7a\u9593\u7fa4\uff08\u203b8\uff09\u306f\u3001\u53cd\u8ee2\u5bfe\u79f0\u6027\u306e\u7834\u308c\u305f\u30ad\u30e9\u30eb\u306aP2\u20812\u20812\u2081\u3067\u3042\u308a\u3001R\u3068S\u3067\u3089\u305b\u3093\u8ef8\u306e\u56de\u8ee2\u65b9\u5411\u304c\u7570\u306a\u308b\u305f\u3081\u3001\u5de6\u53f3\u5186\u504f\u5149\u3092\u9078\u629e\u7684\u306b\u691c\u51fa\u53ef\u80fd\u3067\u3059\u3002\u4e00\u65b9\u3067\u3001P2\u20812\u20812\u2081\u7d50\u6676\u69cb\u9020\u306e\u3089\u305b\u3093\u9396\u306f\u53cd\u5e73\u884c\u306b\u914d\u5217\u3057\u3066\u3044\u308b\u305f\u3081\u3001\u3089\u305b\u3093\u9396\u306b\u6cbf\u3063\u305f\u96fb\u6c17\u53cc\u6975\u5b50\u30e2\u30fc\u30e1\u30f3\u30c8\u306f\u76f8\u6bba\u3055\u308c\u3066\u3057\u307e\u3044\u307e\u3059\u3002\u3053\u3053\u3067\u3001\u4e00\u6b21\u5143\u3089\u305b\u3093\u578b\u30cf\u30ed\u30b2\u30f3\u5316\u925b\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u306e\u7d50\u6676\u5b66\u7684\u5bfe\u79f0\u6027\u3092P2\u2081\u307e\u305f\u306fC2\u306b\u4e0b\u3052\u308b\u3068\u3001\u30d0\u30eb\u30af\u5149\u8d77\u96fb\u529b\u306a\u3069\u306e\u6975\u6027\u306b\u7531\u6765\u3059\u308b\u7269\u6027\u306e\u767a\u73fe\u304c\u671f\u5f85\u3067\u304d\u307e\u3059\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u7d50\u6676\u5bfe\u79f0\u6027\u306e\u5236\u5fa1\u306b\u7126\u70b9\u3092\u3042\u3066\u3001\u71b1\u7684\u5236\u5fa1\u3092\u7528\u3044\u305f\u7d50\u6676\u5316\u6cd5\u306b\u3088\u308a\u3001\u6975\u6027\u30ad\u30e9\u30eb\u7a7a\u9593\u7fa4C2\u306b\u5c5e\u3059\u308b\u4e00\u6b21\u5143\u3089\u305b\u3093\u69cb\u9020\u306e\u30cf\u30ed\u30b2\u30f3\u5316\u925b\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u306e\u7d50\u6676\u3092\u5f97\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\uff08\u56f3\uff12\uff09\u3002\u4e00\u6b21\u5143\u3089\u305b\u3093\u65b9\u5411\u306b\u5927\u304d\u306a\u6975\u6027\u3092\u6709\u3059\u308b\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u7d50\u6676\u306f\u300115V\u306e\u5de8\u5927\u306a\u5149\u8d77\u96fb\u529b\u3092\u793a\u3059\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\uff08\u56f3\uff13\uff09\u3002<\/p>\n<div id=\"attachment_79946\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-79946 size-full\" src=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/795316b92fc766b0181f6fef074f03fa.png\" alt=\"\" width=\"631\" height=\"595\" srcset=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/795316b92fc766b0181f6fef074f03fa.png 631w, https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/795316b92fc766b0181f6fef074f03fa-610x575.png 610w\" sizes=\"auto, (max-width: 631px) 100vw, 631px\" \/><p class=\"wp-caption-text\">\u56f3\uff11\u3000\u6709\u6a5f\u30ad\u30e9\u30eb\u5206\u5b50\u3092\u7528\u3044\u305f\u30e8\u30a6\u5316\u925b\u306e\u4e00\u6b21\u5143\u3089\u305b\u3093\u69cb\u9020\u306e\u5f62\u6210\u30e1\u30ab\u30cb\u30ba\u30e0<\/p><\/div>\n<div id=\"attachment_79945\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-79945 size-full\" src=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/2b530e80c7d0de90885e285c5d798063.png\" alt=\"\" width=\"802\" height=\"415\" srcset=\"https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/2b530e80c7d0de90885e285c5d798063.png 802w, https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/2b530e80c7d0de90885e285c5d798063-610x316.png 610w, https:\/\/www.waseda.jp\/inst\/research\/assets\/uploads\/2025\/03\/2b530e80c7d0de90885e285c5d798063-768x397.png 768w\" sizes=\"auto, (max-width: 802px) 100vw, 802px\" \/><p 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\/>\n\u592a\u967d\u96fb\u6c60\u306e\u5149\u96fb\u5909\u63db\u52b9\u7387\u306f\u3001\u534a\u5c0e\u4f53\u306e\u30d0\u30f3\u30c9\u30ae\u30e3\u30c3\u30d7\u3001\u71b1\u306b\u3088\u308b\u6563\u9038\u3001\u96fb\u8377\u518d\u7d50\u5408\u306a\u3069\u306e\u56e0\u5b50\u306b\u3088\u308a\u5236\u7d04\u3055\u308c\u308b\u3002\u3053\u308c\u3089\u306e\u56e0\u5b50\u3092\u8003\u616e\u3057\u305f\u7406\u8ad6\u7684\u306a\u9650\u754c\u304cShockley\u3068Queisser\u306b\u3088\u308a1961\u5e74\u306b\u793a\u3055\u308c\u305f\u3002<\/p>\n<p>\u203b8\u3000\u7a7a\u9593\u7fa4<br \/>\n\u7d50\u6676\u5185\u306e\u539f\u5b50\u914d\u5217\u306e\u5bfe\u79f0\u6027\u3092\u8a18\u8ff0\u3059\u308b\u305f\u3081\u306e\u6982\u5ff5\u3002\u3059\u3079\u3066\u306e\u7d50\u6676\u304c230\u7a2e\u985e\u3042\u308b\u7a7a\u9593\u7fa4\u306e\u3044\u305a\u308c\u304b\u306b\u5c5e\u3057\u3066\u3044\u308b\u3002<\/p>\n<h3><strong>\u8ad6\u6587\u60c5\u5831<\/strong><\/h3>\n<p>\u96d1\u8a8c\u540d\uff1aAngewandte Chemie International Edition<br \/>\n\u8ad6\u6587\u540d\uff1aGiant Bulk Photovoltaic Effect in a Chiral Polar Crystal based on Helical One-dimensional Lead Halide Perovskites<br \/>\n\u57f7\u7b46\u8005\u540d\uff08\u6240\u5c5e\u6a5f\u95a2\u540d\uff09\uff1a Ayumi Ishii,*[a] Ryohei Sone,[b] Tomohide Yamada,[a] Mizuki Noto,[b] Hikari Suzuki,[a] Daiki Nakamura,[a] Kei Murata,[c] Takuya Shiga,[d] Kazuyuki Ishii,[c] and Masayuki Nihei [d]<br \/>\n[a] Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University<br \/>\n[b] Faculty of Life &amp; Environmental Sciences, Teikyo University of Science<br \/>\n[c] Institute of Industrial Science, The University of Tokyo<br \/>\n[d] Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba<br \/>\n1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan<br \/>\n\u63b2\u8f09\u65e5\uff1a2025\u5e743\u67083\u65e5\uff08\u6708\uff09<br \/>\n\u63b2\u8f09URL\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202424391\" target=\"_blank\" rel=\"noopener\">https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202424391<\/a><br \/>\nDOI\uff1a<a href=\"https:\/\/doi.org\/10.1002\/anie.202424391\" target=\"_blank\" rel=\"noopener\">10.1002\/anie.202424391<\/a><\/p>\n<p><strong>(8)<\/strong><strong>\u7814\u7a76\u52a9\u6210<\/strong><br \/>\n\u7814\u7a76\u8cbb\u540d\uff1aJST \u3055\u304d\u304c\u3051\uff08JPMJPR17P2\uff09CREST \uff08JPMJCR23A1\uff09<br \/>\n\u7814\u7a76\u8ab2\u984c\u540d\uff1a\u4e00\u6b21\u5143\u6709\u6a5f\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u3089\u305b\u3093\u30ca\u30ce\u7269\u8cea\u306b\u3088\u308b\u8fd1\u672a\u6765\u5149\u30c7\u30d0\u30a4\u30b9\u6280\u8853\u306e\u5275\u51fa<br 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