{"id":74755,"date":"2023-07-18T09:50:50","date_gmt":"2023-07-18T00:50:50","guid":{"rendered":"https:\/\/www.waseda.jp\/inst\/research\/?p=74755"},"modified":"2023-07-18T09:51:30","modified_gmt":"2023-07-18T00:51:30","slug":"dehydrogenation-of-methylcyclohexane-using-solid-oxide-fuel-cell-a-smart-energy-conversion%ef%bc%88published-in-applied-energy-june-2023%ef%bc%89%e3%80%8d","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/inst\/research\/news\/74755","title":{"rendered":"Dehydrogenation of methylcyclohexane using solid oxide fuel cell-A smart energy conversion\uff08Published in Applied Energy, June 2023\uff09"},"content":{"rendered":"<table class=\"table table-bordered table-colored-tbhd\" style=\"height: 550px; width: 100%; border-collapse: collapse; border-style: solid;\" border=\"1\">\n<tbody>\n<tr style=\"height: 78px;\">\n<td style=\"width: 16.7893%; height: 78px;\">Journal Title<br \/>\n\/\u63b2\u8f09\u30b8\u30e3\u30fc\u30ca\u30eb\u540d<\/td>\n<td style=\"width: 71.3712%; height: 78px;\">Applied Energy<\/td>\n<\/tr>\n<tr style=\"height: 65px;\">\n<td style=\"width: 16.7893%; height: 80px;\">Publication Year and Month<br \/>\n\/\u63b2\u8f09\u5e74\u6708<\/td>\n<td style=\"width: 71.3712%; height: 80px;\">June, 2023<\/td>\n<\/tr>\n<tr style=\"height: 55px;\">\n<td style=\"width: 16.7893%; height: 79px;\">Paper Title<br \/>\n\/\u8ad6\u6587\u30bf\u30a4\u30c8\u30eb<\/td>\n<td style=\"width: 71.3712%; height: 79px;\">Dehydrogenation of methylcyclohexane using solid oxide fuel cell-A smart energy conversion<\/td>\n<\/tr>\n<tr style=\"height: 85px;\">\n<td style=\"width: 16.7893%; height: 85px;\">DOI<br \/>\n\/\u8ad6\u6587DOI<\/td>\n<td style=\"width: 71.3712%; height: 85px;\"><a href=\"https:\/\/doi.org\/10.1016\/j.apenergy.2023.121469\">10.1016\/j.apenergy.2023.121469<\/a><\/td>\n<\/tr>\n<tr style=\"height: 59px;\">\n<td style=\"width: 16.7893%; height: 80px;\">\u00a0Author of Waseda University<br \/>\n\/\u672c\u5b66\u306e\u8457\u8005<\/td>\n<td style=\"width: 71.3712%; height: 80px;\">FUKUNAGA, Akihiko(Professor(without tenure), Faculty of Science and Engineering, School of Advanced Science and Engineering):First Author, Correspoinding Author<\/td>\n<\/tr>\n<tr style=\"height: 68px;\">\n<td style=\"width: 16.7893%; height: 86px;\">Related Websites<br \/>\n\/\u95a2\u9023Web<\/td>\n<td style=\"width: 71.3712%; height: 86px;\">&#8211;<\/td>\n<\/tr>\n<tr style=\"height: 138px;\">\n<td style=\"width: 16.7893%; height: 148px;\">Abstract<br \/>\n\/\u6284\u9332<\/td>\n<td style=\"width: 71.3712%; height: 148px;\">Dehydrogenation of methylcyclohexane (MCH), a hydrogen carrier, is investigated using a solid oxide fuel cell (SOFC). When an SOFC is operated with a cell temperature of 420\u00a0\u00b0C and a current density of 16\u00a0mA\u00a0cm<sup>\u22122<\/sup>, toluene and benzene, the products of MCH\u2019s dehydrogenation reaction, are observed, with a molar ratio of 94:6. When the cell is operated at 490\u00a0\u00b0C and 90\u00a0mA\u00a0cm<sup>\u22122<\/sup>, in addition of toluene and benzene, 1,4-dioxane is formed at a molar ratio of\u00a0&gt;86%, indicating an oxidative dehydrogenation reaction of MCH. These findings indicate that an SOFC successfully extracts electrons directly from MCH and generates electricity by utilizing the SOFC\u2019s oxygen ion conduction function. The energy required for this process is expected to be less than that required for conventional MCH dehydrogenation. Furthermore, we reveal that SOFCs can be applied to the oxygen displacement reaction of benzene rings.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"<p>Journal Title \/\u63b2\u8f09\u30b8\u30e3\u30fc\u30ca\u30eb\u540d Applied Energy Publication Year and Month \/\u63b2\u8f09\u5e74\u6708 June, 2023 Paper Title \/\u8ad6\u6587\u30bf\u30a4\u30c8\u30eb Dehydro [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[],"tags":[218,217],"class_list":["post-74755","post","type-post","status-publish","format-standard","hentry","tag-impact-en","tag-impact"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/74755","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/comments?post=74755"}],"version-history":[{"count":1,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/74755\/revisions"}],"predecessor-version":[{"id":74757,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/posts\/74755\/revisions\/74757"}],"wp:attachment":[{"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/media?parent=74755"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/categories?post=74755"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.waseda.jp\/inst\/research\/wp-json\/wp\/v2\/tags?post=74755"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}