{"id":68112,"date":"2016-09-30T15:34:06","date_gmt":"2016-09-30T06:34:06","guid":{"rendered":"https:\/\/www.waseda.jp\/inst\/research\/?p=68112"},"modified":"2019-01-18T15:35:00","modified_gmt":"2019-01-18T06:35:00","slug":"%e3%83%9d%e3%82%b1%e3%83%83%e3%83%88%e3%81%ab%e5%85%a5%e3%82%8c%e3%81%a6%e6%8c%81%e3%81%a1%e9%81%8b%e3%81%b9%e3%82%8b-%e3%80%8c%e6%b0%b4%e7%b4%a0%e9%81%8b%e6%90%ac%e3%83%97%e3%83%a9%e3%82%b9%e3%83%81","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/inst\/research\/news\/68112","title":{"rendered":"\u30dd\u30b1\u30c3\u30c8\u306b\u5165\u308c\u3066\u6301\u3061\u904b\u3079\u308b \u300c\u6c34\u7d20\u904b\u642c\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u300d\u958b\u767a\u306b\u6210\u529f"},"content":{"rendered":"

\u30dd\u30b1\u30c3\u30c8\u306b\u5165\u308c\u3066\u6301\u3061\u904b\u3079\u308b\uff01\u300c\u6c34\u7d20\u904b\u642c\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u300d\u958b\u767a\u306b\u6210\u529f
\n\u9ad8\u5727\u30dc\u30f3\u30d9\u306a\u3069\u3067\u306e\u4fdd\u7ba1\u30fb\u904b\u642c\u3084\u7206\u767a\u306e\u5371\u967a\u306a\u3069\u6c34\u7d20\u7279\u6709\u306e\u8ab2\u984c\u3092\u89e3\u6c7a<\/h3>\n

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\u4eca\u56de\u306e\u7814\u7a76\u3067\u306f\u3001\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u30b7\u30fc\u30c8\u3068\u3057\u3066\u6210\u5f62\u3067\u304d\u308b\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u3092\u6c34\u306b\u6d78\u3057-1.5V\u306e\u96fb\u5727\u3092\u304b\u3051\u308b\u3068\u3001\u6c34\u7d20\uff082H\uff09\u304c\u56fa\u5b9a\u3055\u308c\u305f\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u304c\u751f\u6210\u3055\u308c\u308b\u3053\u3068\u3092\u767a\u898b\u3057\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u309280\u2103\u3067\u52a0\u6e29\u3059\u308b\u3068\u6c34\u7d20\u30ac\u30b9\u3092\u653e\u51fa\u3057\u3001\u6c34\u7d20\u306e\u56fa\u5b9a\u3068\u653e\u51fa\u306e\u30b5\u30a4\u30af\u30eb\u3092\u7c21\u6613\u306b\u7e70\u308a\u8fd4\u305b\u308b\u3053\u3068\u304c\u5206\u304b\u308a\u307e\u3057\u305f\u3002\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u3001\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u306f\u3068\u3082\u306b\u3001\u5ba4\u6e29\u30fb\u5927\u6c17\u4e0b\u3067\u9577\u671f\u4fdd\u5b58\u304c\u53ef\u80fd\u3067\u3059\u3002\u305d\u306e\u305f\u3081\u3001\u4f8b\u3048\u3070\u3001\u6c34\u7d20\u3092\u8caf\u8535\u3057\u305f\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u3092\u30dd\u30b1\u30c3\u30c8\u306b\u5165\u308c\u3066\u6301\u3061\u904b\u3076\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n

\"20160930_fig1\"<\/p>\n

\u672c\u7814\u7a76\u6210\u679c\u306f\u3001\u8eab\u8fd1\u306a\u5834\u6240\u3067\u306e\u6c34\u7d20\u8caf\u8535\u3092\u53ef\u80fd\u306b\u3057\u3001\u5730\u57df\u5206\u6563\u578b\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u30b7\u30b9\u30c6\u30e0\u69cb\u7bc9\u306b\u8ca2\u732e\u3059\u308b\u3053\u3068\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n

\u306a\u304a\u3001\u4eca\u56de\u306e\u7814\u7a76\u6210\u679c\u306f\u3001\u82f1\u56fd\u79d1\u5b66\u96d1\u8a8c\u300eNature Communications\u300f\u306b\u3001\u65e5\u672c\u6642\u95939\u6708\uff13\uff10\u65e5\u5348\u5f8c6\u6642\uff08\u73fe\u5730\u6642\u95939\u670830\u65e5\u5348\u524d\uff11\uff10\u6642\uff09\u306b\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n

\u8ad6\u6587\u540d\uff1aA ketone\/alcohol polymer for cycle of electrolytic hydrogen-fixing with water and releasing under mild conditions<\/a><\/p>\n

(1)\u3053\u308c\u307e\u3067\u306e\u7814\u7a76\u3067\u5206\u304b\u3063\u3066\u3044\u305f\u3053\u3068\uff08\u79d1\u5b66\u53f2\u7684\u30fb\u6b74\u53f2\u7684\u306a\u80cc\u666f\u306a\u3069\uff09<\/h4>\n

\u300c\u6c34\u7d20\u300d\u3092\u30a8\u30cd\u30eb\u30ae\u30fc\u6e90\u306e\u4e00\u3064\u3068\u3059\u308b\u793e\u4f1a\u306e\u5b9f\u73fe\u306b\u5411\u3051\u3066\u3001\u65bd\u7b56\u3068\u7814\u7a76\u30fb\u958b\u767a\u304c\u9032\u3093\u3067\u3044\u308b\u3002\u3057\u304b\u3057\u3001\u6c34\u7d20\u306f\u9ad8\u5727\u30dc\u30f3\u30d9\u306a\u3069\u3067\u306e\u4fdd\u7ba1\u30fb\u904b\u642c\u3084\u7206\u767a\u306e\u5371\u967a\u306a\u3069\u8ab2\u984c\u304c\u591a\u304f\u3001\u5b89\u5168\u3067\u52b9\u7387\u306e\u826f\u3044\u6c34\u7d20\u30ad\u30e3\u30ea\u30a2(\u904b\u642c\u4f53)\u306e\u958b\u767a\u304c\u671b\u307e\u308c\u3066\u3044\u308b\u3002\u6709\u6a5f\u7269\u306e\u4e2d\u306b\u306f\u5316\u5b66\u7d50\u5408\u3067\u6c34\u7d20\u3092\u56fa\u5b9a\u3057\u3001\u307e\u305f\u653e\u51fa\u3059\u308b\u3082\u306e\u304c\u3042\u308b\uff08\u4f8b\u3048\u3070\u30a2\u30f3\u30e2\u30cb\u30a2\uff08NH3<\/sub>\uff09\u306f\u7a92\u7d20\uff08N2<\/sub>\uff09\u306b\u6c34\u7d20\u30ac\u30b9\uff08H2<\/sub>\uff09\u304c\u56fa\u5b9a\u3055\u308c\u751f\u6210\uff09\u3002\u3057\u304b\u3057\u6c34\u7d20\u306e\u56fa\u5b9a\u30fb\u53d6\u308a\u51fa\u3057\u306b\u306f\u9ad8\u6e29\u30fb\u9ad8\u5727\u3092\u8981\u3057\u3001\u63ee\u767a\u30fb\u6bd2\u6027\u306a\u3069\u306e\u89b3\u70b9\u304b\u3089\u3082\u6271\u3044\u306f\u5bb9\u6613\u3067\u306f\u306a\u3044\u3002<\/p>\n

(2)\u4eca\u56de\u306e\u7814\u7a76\u3067\u65b0\u305f\u306b\u5b9f\u73fe\u3057\u3088\u3046\u3068\u3057\u305f\u3053\u3068\u3001\u660e\u3089\u304b\u306b\u306a\u3063\u305f\u3053\u3068<\/h4>\n

\u6c34\u7d20\u306e\u8caf\u8535\u30fb\u904b\u642c\u30fb\u653e\u51fa\u306b\u304a\u3044\u3066\u30a8\u30cd\u30eb\u30ae\u30fc\u8ca0\u8377\u304c\u5c11\u306a\u304f\u3001\u304b\u3064\u5b89\u5168\u3067\u8efd\u91cf\u306a\u3001\u307e\u3063\u305f\u304f\u65b0\u3057\u3044\u5f62\u5f0f\u306e\u6c34\u7d20\u30ad\u30e3\u30ea\u30a2(\u904b\u642c\u4f53)\u3092\u5b9f\u73fe\u3057\u3088\u3046\u3068\u3057\u305f\u3002<\/p>\n

(3)\u305d\u306e\u305f\u3081\u306b\u65b0\u3057\u304f\u958b\u767a\u3057\u305f\u624b\u6cd5<\/h4>\n

\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u30b7\u30fc\u30c8\u3068\u3057\u3066\u6210\u5f62\u3067\u304d\u308b\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u3092\u6c34\u306b\u6d78\u3057-1.5 V\u306e\u96fb\u5727\u3092\u304b\u3051\u308b\u3068\u3001\u5316\u5b66\u7d50\u5408\u306b\u3088\u3063\u3066\u6c34\u304b\u3089\u30d7\u30ed\u30c8\u30f3\u304c\u53d6\u308a\u8fbc\u307e\u308c\u3001\u6c34\u7d20(2H)\u304c\u56fa\u5b9a\u3055\u308c\u305f\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u304c\u751f\u6210\u3055\u308c\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u305f\u3002\u3055\u3089\u306b\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u306f80\u2103\u306e\u52a0\u6e29\u306b\u3088\u308a\u6c34\u7d20\u30ac\u30b9\u3092\u653e\u51fa\u3057\u305f\u3002\u6c34\u7d20\u56fa\u5b9a\u3068\u653e\u51fa\u306e\u30b5\u30a4\u30af\u30eb\u306f\u6e29\u548c\u306a\u6761\u4ef6\u4e0b\u3067\u7c21\u6613\u306b\u9032\u307f\u3001\u7e70\u308a\u8fd4\u305b\u305f\u3002<\/p>\n

(4)\u4eca\u56de\u306e\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f\u7d50\u679c\u53ca\u3073\u77e5\u898b<\/h4>\n
    \n
  1. \u300c\u6c34\u300d\u3092\u30d7\u30ed\u30c8\u30f3\u6e90\u3068\u3057\u3066\u6c34\u7d20(2H)\u3092\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u306b\u56fa\u5b9a\u3067\u304d\u305f\u3002\u6c34\u7d20\u3092\u30a2\u30eb\u30b3\u30fc\u30eb\u30dd\u30ea\u30de\u30fc\u306e\u5f62\u3067\u8caf\u8535\u3002\u3053\u306e\u30d7\u30ed\u30bb\u30b9\u306f-1.5V\u306e\u96fb\u5727\u5370\u52a0(\u7c21\u6613\u3001\u4e00\u6642\u9593\u7a0b\u5ea6)\u3067\u9032\u3080\u3002<\/li>\n
  2. 80\u2103\u306e\u52a0\u6e29\u306b\u3088\u308a\u6c34\u7d20\u30ac\u30b9\u304c\u767a\u751f\u3057\u3001\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u306b\u623b\u308b\u30021g\u306e\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u304b\u3089\u7d0430mL\u306e\u6c34\u7d20\u30ac\u30b9\u304c\u767a\u751f(\u4e00\u6642\u9593\u7a0b\u5ea6)\u3059\u308b\u3002<\/li>\n
  3. \u4e0a\u8a18\u306e\u6c34\u7d20\u56fa\u5b9a-\u6c34\u7d20\u767a\u751f\u306f\u7e70\u308a\u8fd4\u305b\u308b(50\u56de\u8a66\u9a13\u3001\u6027\u80fd\u6e1b\u5c11\u306f\u308f\u305a\u304b)\u3002<\/li>\n
  4. \u30a2\u30eb\u30b3\u30fc\u30eb\u3001\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u306f\u3068\u3082\u306b\u5b89\u5b9a\u3001\u5ba4\u6e29\u30fb\u5927\u6c17\u4e0b\u3067\u9577\u671f\u4fdd\u5b58\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd(\u4e00\u30f5\u6708\u5f8c\u3082\u5909\u6027\u306a\u3057)\u3002<\/li>\n<\/ol>\n

    (5)\u7814\u7a76\u306e\u6ce2\u53ca\u52b9\u679c\u3084\u793e\u4f1a\u7684\u5f71\u97ff<\/h4>\n
      \n
    1. \u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u3068\u3057\u3066\u6bd2\u6027\u30fb\u63ee\u767a\u6027\u306a\u3057\u3001\u9632\u7206\u4e0d\u8981\u3001\u5b89\u5168\u3002<\/li>\n
    2. \u8efd\u91cf\u3001\u6210\u5f62\u6027\u3001\u904b\u642c\u30fb\u4fdd\u5b58\u304c\u5bb9\u6613\u3002<\/li>\n
    3. \u6c34\u304b\u3089\u5ba4\u6e29\u3067\u306e\u96fb\u89e3\u306b\u3088\u308a\u6c34\u7d20\u3092\u56fa\u5b9a\u3059\u308b\u305f\u3081\u3001\u6c34\u7d20\u30ac\u30b9\u3092\u539f\u6599\u3068\u305b\u305a\u3001\u307e\u305f\u3001\u9ad8\u6e29\u9ad8\u5727\u3092\u8981\u3057\u306a\u3044\u3002<\/li>\n<\/ol>\n

      \u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u3068\u3057\u3066\u3001\u6c34\u7d20\u3092\u8caf\u3081\u3066\u3044\u308b\u72b6\u614b\u3067\u3082\u624b\u3067\u89e6\u308b\u3053\u3068\u304c\u3067\u304d\u3001\u4f8b\u3048\u3070\u30dd\u30b1\u30c3\u30c8\u306b\u5165\u308c\u3066\u6301\u3061\u904b\u3079\u308b\u3002\u8eab\u8fd1\u306a\u5834\u6240\u3067\u306e\u6c34\u7d20\u8caf\u8535(\u5730\u57df\u5206\u6563\u578b)\u6750\u6599\u306a\u3069\u3068\u3057\u3066\u306e\u5c55\u958b\u304c\u671f\u5f85\u3067\u304d\u308b\u3002<\/p>\n

      (6)\u4eca\u5f8c\u306e\u8ab2\u984c<\/h4>\n

      \u8cea\u91cf\u6c34\u7d20\u5bc6\u5ea6(1.1 wt%)\u304c\u4f4e\u3044\u3053\u3068\u304c\u8ab2\u984c\u3067\u3042\u308a\u3001\u3088\u308a\u30b3\u30f3\u30d1\u30af\u30c8\u306a\u5206\u5b50\u69cb\u9020\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u3001\u30b1\u30c8\u30f3\u30dd\u30ea\u30de\u30fc\u3067\u691c\u8a0e\u4e2d\u3067\u3042\u308b\u3002<\/p>\n

       <\/p>\n","protected":false},"excerpt":{"rendered":"

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