{"id":2061,"date":"2020-10-29T15:34:13","date_gmt":"2020-10-29T06:34:13","guid":{"rendered":"https:\/\/www.waseda.jp\/inst\/nanolife\/?p=2061"},"modified":"2020-11-09T12:21:03","modified_gmt":"2020-11-09T03:21:03","slug":"%e3%83%a0%e3%83%bc%e3%83%b3%e3%82%b7%e3%83%a7%e3%83%83%e3%83%88%e5%9e%8b%e7%a0%94%e7%a9%b6%e9%96%8b%e7%99%ba%e5%88%b6%e5%ba%a6%e3%83%97%e3%83%ad%e3%82%b8%e3%82%a7%e3%82%af%e3%83%88%e3%83%9e%e3%83%8d-2","status":"publish","type":"post","link":"https:\/\/www.waseda.jp\/inst\/nanolife\/news\/2020\/10\/29\/2061\/","title":{"rendered":"\u8ad6\u6587\u63b2\u8f09\uff1a\u30de\u30a4\u30af\u30ed\u30b9\u30b1\u30fc\u30eb\u306e\u5fae\u5c0f\u6db2\u6ef4\u5185\u3067\u30a2\u30be\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u6210\u529f"},"content":{"rendered":"

\u7814\u7a76\u306e\u6982\u8981<\/h3>\n

\u65e9\u7a32\u7530\u5927\u5b66\u7406\u5de5\u5b66\u8853\u9662\u306e\u5e84\u5b50\u7fd2\u4e00\uff08\u3057\u3087\u3046\u3058\u3057\u3085\u3046\u3044\u3061\uff09\u6559\u6388\u3001\u65e9\u7a32\u7530\u5927\u5b66\u30ca\u30ce\u30fb\u30e9\u30a4\u30d5\u5275\u65b0\u7814\u7a76\u6a5f\u69cb\u306e\u7530\u4e2d\u5927\u5668\uff08\u305f\u306a\u304b\u3060\u3044\u304d\uff09\u6b21\u5e2d\u7814\u7a76\u54e1\uff08\u7814\u7a76\u9662\u8b1b\u5e2b\uff09\u3089\u306e\u7814\u7a76\u30c1\u30fc\u30e0\u306f\u3001\u30de\u30a4\u30af\u30ed\u30b9\u30b1\u30fc\u30eb\u306e\u5fae\u5c0f\u6db2\u6ef4\u5185\u3067\u30a2\u30be\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u5f93\u6765\u6cd5\u3068\u6bd4\u8f03\u3059\u308b\u3068\u3001pH\u6fc3\u5ea6\u304c1\/10\u306b\u307e\u3067\u4e0b\u304c\u308a\u3001\u5408\u6210\u6642\u9593\u30821\/1000\u4ee5\u4e0b\u3068\u306a\u308a\u30d3\u30fc\u30ab\u30fc\u3068\u306f\u5168\u304f\u7570\u306a\u308b\u5408\u6210\u6761\u4ef6\u3068\u306a\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u7530\u4e2d\u5927\u5668\u6b21\u5e2d\u7814\u7a76\u54e1\u306b\u3088\u3063\u3066\u767a\u8868\u3055\u308c\u305f\u7814\u7a76\u6210\u679c\u306f\u3001\u82f1\u56fd\u738b\u7acb\u5316\u5b66\u4f1a\u304c\u767a\u884c\u3059\u308b\u79d1\u5b66\u30b8\u30e3\u30fc\u30ca\u30eb”RSC Advances<\/a>“<\/em>\u306b\u8ad6\u6587\u3068\u3057\u3066\u63b2\u8f09\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n

 <\/p>\n

\u7814\u7a76\u306e\u5185\u5bb9<\/h3>\n

\u73fe\u5728\u306e\u5316\u5b66\u5408\u6210\u306f\u3001\u53cd\u5fdc\u6027\u306e\u4f4e\u3044\u5408\u6210\u30b9\u30ad\u30fc\u30e0\uff08\u203b1\uff09\u306b\u5bfe\u3057\u3066\u3001\u71b1\u3001\u89e6\u5a92\u3001\u8a66\u85ac\u6fc3\u5ea6\u3001\u5149\u3001\u53cd\u5fdc\u6642\u9593\u304a\u3088\u3073\u53cd\u5fdc\u7d4c\u8def\u7b49\u306e\u5de5\u592b\u306b\u3088\u308a\u5408\u6210\u6cd5\u3092\u69cb\u7bc9\u3057\u3066\u3044\u307e\u3059\u3002\u3057\u304b\u3057\u3001\u5f93\u6765\u306e\u65b9\u6cd5\u306f\u5927\u304d\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u8981\u3057\u305f\u308a\u3001\u8cb4\u91cd\u8a66\u85ac\u306e\u5927\u91cf\u6d88\u8cbb\u3001\u74b0\u5883\u6c5a\u67d3\u7b49\u306e\u554f\u984c\u3092\u62b1\u3048\u3066\u3044\u307e\u3059\u3002\u307e\u305f\u3001\u3053\u308c\u3089\u306e\u53cd\u5fdc\u6761\u4ef6\u3092\u99c6\u4f7f\u3057\u3066\u3082\u5408\u6210\u306b\u81f3\u3063\u3066\u3044\u306a\u3044\u5316\u5408\u7269\u3082\u591a\u3005\u3042\u308a\u3001\u65b0\u305f\u306a\u5408\u6210\u30b9\u30ad\u30fc\u30e0\u306e\u69cb\u7bc9\u306f\u55ab\u7dca\u306e\u8ab2\u984c\u3068\u306a\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n

\u65e9\u7a32\u7530\u5927\u5b66\u30ca\u30ce\u30fb\u30e9\u30a4\u30d5\u5275\u65b0\u7814\u7a76\u6a5f\u69cb\u30fb\u7530\u4e2d\u6b21\u5e2d\u7814\u7a76\u54e1\u3089\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u5834\u3092\u5c0f\u3055\u304f\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u5316\u5b66\u53cd\u5fdc\u6027\u3092\u5411\u4e0a\u3055\u305b\u308b\u7814\u7a76\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002\u5fae\u5c0f\u9818\u57df\u306b\u304a\u3051\u308b\u5316\u5b66\u53cd\u5fdc\u3067\u306f\u3001\u5316\u5b66\u7a2e\u306e\u62e1\u6563\u6642\u9593\u304c\u65e9\u3044\u305f\u3081\u306b\u5316\u5b66\u5408\u6210\u304c\u65e9\u304f\u9032\u884c\u3059\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u3053\u308c\u307e\u3067\u3001\u30de\u30a4\u30af\u30ed\u6d41\u4f53\u30c7\u30d0\u30a4\u30b9(\u203b2)\u3092\u7528\u3044\u3066\u91d1\u5c5e\u932f\u4f53\u306e\u5408\u6210\u3092\u884c\u3044\u3001\u5fae\u5c0f\u9818\u57df\u4e2d\u306e\u5316\u5b66\u53cd\u5fdc\u901f\u5ea6\u306b\u95a2\u3059\u308b\u7814\u7a76\u3092\u884c\u3063\u3066\u304d\u307e\u3057\u305f\u3002\u5fae\u5c0f\u9818\u57df\u4e2d\u3067\u91d1\u5c5e\u932f\u4f53\u3092\u5408\u6210\u3059\u308b\u3068\u3001\u5f93\u6765\u6cd5\uff08\u30d3\u30fc\u30ab\u30fc\uff09\u3068\u6bd4\u8f03\u3057\u30661\u4e07\u500d\u4ee5\u4e0a\u5316\u5b66\u53cd\u5fdc\u6642\u9593\u304c\u77ed\u7e2e\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f(D. Tanaka, S. Shoji, RSC Adv., 2016, 6, 81862\u201381868)\u3002
\n\u2500\u2500\u2500\u2500\u2500\u2500
\n\u672c\u7814\u7a76\u3067\u306f\u3001\u5fae\u5c0f\u9818\u57df\u4e2d\u306e\u53cd\u5fdc\u5834\u306e\u7279\u6027\u3092\u5fdc\u7528\u3057\u3066\u8907\u96d1\u306a\u5408\u6210\u64cd\u4f5c\u304c\u8981\u6c42\u3055\u308c\u308b\u5316\u5b66\u5408\u6210\u3092\u884c\u3044\u307e\u3057\u305f\u3002<\/p>\n

\u5177\u4f53\u7684\u306b\u306f\u3001\u30de\u30a4\u30af\u30ed\u6d41\u4f53\u30c7\u30d0\u30a4\u30b9\u3092\u7528\u3044\u3066\u30de\u30a4\u30af\u30ed\u30c9\u30ed\u30c3\u30d7\u30ec\u30c3\u30c8(\u203b3)\u3092\u751f\u6210\u3057\u30c9\u30ed\u30c3\u30d7\u30ec\u30c3\u30c8\u5185\u90e8\u3067\u30a2\u30be\u5316\u5408\u7269(\u203b4)\u3092\u5408\u6210\u3057\u307e\u3057\u305f\u3002\u5fae\u5c0f\u9818\u57df\u4e2d\u3067\u306f\u3001\u5316\u5b66\u5408\u6210\u306e\u53cd\u5fdc\u901f\u5ea6\u306e\u5411\u4e0a\u306e\u4ed6\u306b\u3001pH\u8a66\u85ac\u306e\u6fc3\u5ea6\u6761\u4ef6\u304c\u5f93\u6765\u6cd5\u3068\u7570\u306a\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002\u5f93\u6765\u306e\u30a2\u30be\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u306f\u9ad8\u6fc3\u5ea6\u306e\u5869\u9178\uff085.6 mol L-1\uff09\u304c\u7528\u3044\u3089\u308c\u307e\u3059\u304c\u3001\u672c\u7814\u7a76\u3067\u306f\u3001\u5869\u9178\u306e\u6fc3\u5ea6\u304c0.5 mol L-1\u3068\u30d3\u30fc\u30ab\u30fc\u306e10\u5206\u306e1\u4ee5\u4e0b\u3067\u30a2\u30be\u5316\u5408\u7269\u304c\u5408\u6210\u3055\u308c\u307e\u3057\u305f\uff08\u56f3\uff11(a)\uff09\u3002\u30de\u30a4\u30af\u30ed\u30c9\u30ed\u30c3\u30d7\u30ec\u30c3\u30c8\u3092\u7528\u3044\u3066\u5408\u6210\u3055\u308c\u305f\u751f\u6210\u7269\u306f\u3001\u8d64\u5916\u5206\u5149\u6cd5\u3084\u8cea\u91cf\u5206\u6790\u6cd5\u3001NMR\u306a\u3069\u306b\u3088\u308a\u5206\u6790\u3055\u308c\u307e\u3057\u305f\uff08\u56f3\uff11(b)\uff09\u3002<\/p>\n

\"\"<\/a>

\u56f31. (a)\u30a2\u30be\u5316\u5408\u7269\u306e\u751f\u6210\u306e\u69d8\u5b50\uff08bar: 200 \u03bcm\uff09\u3001(b)NMR\u306b\u3088\u308b\u5316\u5408\u7269\u306e\u540c\u5b9a\u7d50\u679c<\/p><\/div>\n

\u672c\u7814\u7a76\u306b\u3088\u308a\u3001\u5316\u5b66\u53cd\u5fdc\u5834\u306e\u5927\u304d\u3055\u3092\u30de\u30a4\u30af\u30ed\u30b9\u30b1\u30fc\u30eb\u306b\u5c0f\u3055\u304f\u3059\u308b\u3060\u3051\u3067\u5408\u6210\u6642\u306epH\u6761\u4ef6\u304c\u5927\u304d\u304f\u5909\u5316\u3059\u308b\u3053\u3068\u3092\u4e16\u754c\u3067\u521d\u3081\u3066\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002
\n\u2500\u2500\u2500\u2500\u2500\u2500
\n\u30a2\u30be\u5316\u5408\u7269\u306e\u5408\u6210\u3067\u306f\u3001\u56f3\uff12(a)\u306b\u793a\u3059\u3088\u3046\u306b\u9178\u6027\u3001\u30a2\u30eb\u30ab\u30ea\u6027\u3001\u4e2d\u6027\u30683\u6bb5\u968e\u306e\u7cbe\u5bc6\u306apH\u30b3\u30f3\u30c8\u30ed\u30fc\u30eb\u304c\u8981\u6c42\u3055\u308c\u307e\u3059\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u30de\u30a4\u30af\u30ed\u30c9\u30ed\u30c3\u30d7\u30ec\u30c3\u30c8\u5185\u90e8\u306e\u5408\u6210\u74b0\u5883\u3092\u53b3\u5bc6\u306b\u30b3\u30f3\u30c8\u30ed\u30fc\u30eb\u304c\u53ef\u80fd\u306a\u30de\u30a4\u30af\u30ed\u6d41\u4f53\u30c7\u30d0\u30a4\u30b9\u3092\u958b\u767a\u3057\u307e\u3057\u305f\u3002\u30c7\u30d0\u30a4\u30b9\u306e\u6982\u5ff5\u56f3\u3092\u56f3\uff12(b)\u306b\u793a\u3057\u307e\u3059\u3002\u307e\u305a\u3001\u9178\u6027\u30a8\u30ea\u30a2\u3067\u30b8\u30a2\u30be\u5316\u53cd\u5fdc\u304c\u9032\u884c\u3057\u3001\u305d\u306e\u5f8c\u3001\u30a2\u30eb\u30ab\u30ea\u6027\u306b\u8abf\u6574\u3055\u308c\u305fo-\u30d0\u30cb\u30ea\u30f3\u304c\u52a0\u3048\u3089\u308c\u3066\u30c9\u30ed\u30c3\u30d7\u30ec\u30c3\u30c8\u5185\u90e8\u304c\u77ac\u6642\u306b\u4e2d\u6027\u306b\u30b3\u30f3\u30c8\u30ed\u30fc\u30eb\u3055\u308c\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u6700\u7d42\u76ee\u7684\u751f\u6210\u7269\u3067\u3042\u308b\u30a2\u30be\u5316\u5408\u7269\u304c\u5408\u6210\u3055\u308c\u307e\u3059\u3002\u30de\u30a4\u30af\u30ed\u6d41\u4f53\u30c7\u30d0\u30a4\u30b9\u306f\u8010\u85ac\u54c1\u6027\u306e\u9ad8\u3044PDMS(polydimethylsiloxane)\u3068\u30ac\u30e9\u30b9\u304b\u3089\u4f5c\u88fd\u3057\u307e\u3057\u305f\uff08\u56f32(c)\uff09\u3002<\/p>\n

\"\"<\/a>

\u56f3\uff12. (a)\u30a2\u30be\u5316\u5408\u7269\u306e\u5408\u6210\u30b9\u30ad\u30fc\u30e0\u3001(b)\u5b9f\u9a13\u306e\u6982\u8981\u3001(c)\u5b9f\u9a13\u306b\u4f7f\u7528\u3057\u305f\u30de\u30a4\u30af\u30ed\u6d41\u4f53\u30c7\u30d0\u30a4\u30b9<\/p><\/div>\n

\u2500\u2500\u2500\u2500\u2500\u2500
\n\u672c\u7814\u7a76\u306b\u3088\u308a\u5fae\u5c0f\u9818\u57df\u5834\u3067\u306f\u5316\u5b66\u53cd\u5fdc\u306epH\u6761\u4ef6\u304c\u5927\u5e45\u306b\u5909\u5316\u3059\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u5316\u5b66\u53cd\u5fdc\u6761\u4ef6\u306e\u5909\u5316\u306f\u69d8\u3005\u306a\u5206\u91ce\u3067\u5fdc\u7528\u304c\u53ef\u80fd\u3067\u3059\u3002\u4f8b\u3048\u3070\u3001\u5275\u85ac\u306e\u969b\u306b\u9ad8\u6fc3\u5ea6\u306epH\u8a66\u85ac\u306b\u3088\u308a\u5316\u5b66\u69cb\u9020\u304c\u58ca\u308c\u3066\u3057\u307e\u3046\u305f\u3081\u5275\u308a\u51fa\u305b\u306a\u304b\u3063\u305f\u65b0\u85ac\u306e\u958b\u767a\u306b\u5fdc\u7528\u3067\u304d\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u307e\u305f\u3001\u690d\u7269\u3084\u4eba\u4f53\u5185\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u306f\u672a\u89e3\u660e\u306a\u90e8\u5206\u304c\u591a\u3044\u3067\u3059\u304c\u3001\u5fae\u5c0f\u9818\u57df\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u306e\u7279\u7570\u6027\u3092\u89e3\u660e\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u751f\u4f53\u5185\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u306b\u306a\u308b\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n

\u4eca\u5f8c\u306e\u8ab2\u984c\u3068\u7814\u7a76\u8005\u306e\u898b\u89e3<\/h4>\n

\u73fe\u5728\u306e\u5fae\u5c0f\u5316\u5b66\u53cd\u5fdc\u5834\u306f100\u30de\u30a4\u30af\u30ed\u30b9\u30b1\u30fc\u30eb\u3067\u5408\u6210\u5b9f\u9a13\u304c\u5b9f\u65bd\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u305d\u308c\u3088\u308a\u3082\u5c0f\u3055\u304410\u30de\u30a4\u30af\u30ed\u30b9\u30b1\u30fc\u30eb\u4ee5\u4e0b\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u306f\u672a\u958b\u306e\u9818\u57df\u3067\u3059\u3002<\/p>\n

\u4eca\u5f8c\u306f\u300110 \u03bcm\u4ee5\u4e0b\u306e\u8d85\u5fae\u5c0f\u306a\u9818\u57df\u3067\u69d8\u3005\u306a\u5316\u5b66\u53cd\u5fdc\u3092\u884c\u3044\u201d\u8d85\u5fae\u5c0f\u9818\u57df\u5834\u201d\u7279\u6709\u306e\u3055\u3089\u306a\u308b\u5316\u5b66\u53cd\u5fdc\u306e\u7279\u7570\u6027\u3092\u63a2\u7a76\u3057\u3066\u3044\u304d\u307e\u3059\u3002<\/p>\n

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