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  • 2012
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Last update: March 2012

Papers Published in 2012


Electrochemical Synthesis of Mesoporous Pt-Au Binary Alloys with Tunable Compositions for Enhancement of Electrochemical Performance
Yusuke Yamauchi, Akihisa Tonegawa, Masaki Komatsu, Hongjing Wang, Liang Wang, Yoshihiro Nemoto, Norihiro Suzuki, and Kazuyuki Kuroda
J. Am. Chem. Soc., in press.


A spherosilicate oligomer with eight stable silanol groups as a building block of hybrid materials
Kazufumi Kawahara, Hiroki Tachibana, Yoshiaki Hagiwara, and Kazuyuki Kuroda
New J. Chem., Advance Article.


Preparation of Ni nanoparticles between montmorillonite layers utilizing dimethylaminoborane as reducing agent
Yusuke Yamauchi, Tetsuro Itagaki, Tokihiko Yokoshima and Kazuyuki Kuroda
Dalton Trans, 41, 1210–1215 (2012).

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Polymorph Control of Calcium Carbonate on the Surface of Mesoporous Silica
Kwang-Min CHOI, and Kazuyuki Kuroda
Cryst. Growth Des., 12, 887-893 (2012).

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Uniform and high dispersion of gold nanoparticles on imogolite nanotubes and assembly into morphologically controlled materials
Yoshiyuki Kuroda, Kohta Fukumoto, and Kazuyuki Kuroda
Appl. Clay Sci., 55, 10-17 (2012).

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A Novel Preparative Method of Silica Nanotubes by Utilizing Self-assembly and Disassembly of Peptide Amphiphiles
Tomoko Shimada, Yasuhiro, Tamura, Matthew Tirrell, and Kazuyuki Kuroda
Chem. Lett., 41, 95­97 (2012).

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Papers Published in 2011


Dendritic, Nanosized Building Block for Siloxane-Based Materials: A Spherosilicate Dendrimer
Kazufumi Kawahara, Yoshiaki Hagiwara, and Kazuyuki Kuroda
Chem. Eur. J., 17, 13188–13196 (2011).

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Practical Conversion of Chlorosilane into Alkoxysilanes without Generating HCl
Ryutaro Wakabayashi, Yasushi Sugiura, Toshimichi Shibue, and Kazuyuki Kuroda
Angew. Chem. Int. Ed., 50, 10708–10711 (2011).

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Materials design of layered silicates through covalent modification of interlayer surfaces
Nobuyuki Takahashi, and Kazuyuki Kuroda
J. Mater. Chem., 21, 14336–14353 (2011).



Double function of tris(hydroxymethyl)aminomethane (THAM) for the preparation of colloidal silica nanospheres and the conversion to ordered mesoporous carbon
Kwang-Min Choi and Kazuyuki Kuroda
Chem. Commun., 47, 10933-10935 (2011).



Ordered Silylation of Layered Silicate RUB-51 with Half-Sodalite Cages
Yusuke Asakura, Yuki Matsuo, Nobuyuki Takahashi, and Kazuyuki Kuroda
Bull. Chem. Soc. Jpn., 84, 968-975 (2011).



Remarkable Birefringence in a TiO2-SiO2 Composite Film with an Aligned Mesoporous Structure
Hirokatsu Miyata, Yuta Fukushima, Kohei Okamoto, Masahiko Takahashi, Masatoshi Watanabe, Wataru Kubo, Atsushi Komoto, Shin Kitamura, Yosuke Kanno, and Kazuyuki Kuroda
J. Am. Chem. Soc., 133, 13539-13544 (2011).



Aqueous Colloidal Mesoporous Nanoparticles with Ethenylene-Bridged Silsesquioxane Frameworks
Chihiro Urata, Hironori Yamada, Ryutaro Wakabayashi, Yuko Aoyama, Shota Hirosawa, Satoshi Arai, Shinji Takeoka, Yusuke Yamauchi, and Kazuyuki Kuroda
J. Am. Chem. Soc., 133, 8102-8105 (2011).



Pt nanoworms: creation of a bumpy surface on one-dimensional (1D) Pt nanowires with the assistance of surfactants embedded in mesochannels
Azusa Takai, Hamed Ataee-Esfahani, Yoji Doi, Minekazu Fuziwara, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Commun., 47, 7701-7703 (2011).



TEM image simulation of mesoporous crystals for structure type identification
Tetsu Ohsuna, Yasuhiro Sakamoto, Osamu Terasaki and Kazuyuki Kuroda
Solid State Sci., 13, 736-744 (2011).



Enlargement of mesopores of 2-D orthorhombic KSW-2 type silica by the addition of poly(oxyethylene) alkyl ether during the mesostructural formation
Nobuyuki Takahashi, Tatsuo Kimura and Kazuyuki Kuroda
Solid State Sci., 13, 714-720 (2011).



Synthesis of mesostructured silica from monoalkyl-substituted double five-ring units
Atsushi Shimojima, Hideki Kuge and Kazuyuki Kuroda
J. Sol-Gel Sci. Technol., 57, 263-268 (2011).



Usefulness of alkoxyltitanosiloxane for the preparation of mesoporous silica containing a large amount of isolated titanium
Kwang-Min Choi, Ryutaro Wakabayashi, Takashi Tatsumi, Toshiyuki Yokoi, Kazuyuki Kuroda
J. Colloid Interface Sci., 359, 240-247 (2011).



Preparation of mesostructured silica-micelle hybrids and their conversion to mesoporous silica modified controllably with immobilized hydrophobic blocks by using triethoxysilyl-terminated PEO-PPO-PEO triblock copolymer
Chihiro Urata, Yasuhiro Tamura, Yusuke Yamauchi, and Kazuyuki Kuroda
J. Mater. Chem., 21, 3711-3717 (2011).



One-Step Exfoliation of Kaolinites and Their Transformation into Nanoscrolls
Yoshiyuki Kuroda, Kazuyuki Ito, Kenichi Itabashi, and Kazuyuki Kuroda
Langmuir, 27, 2028-2035 (2011).



A Rational Repeating Template Method for Synthesis of 2D Hexagonally Ordered Mesoporous Precious Metals
Azusa Takai, Yoji Doi, Yusuke Yamauchi, and Kazuyuki Kuroda
Chem. Asian J., 6, 881-887 (2011).



Exfoliation of Layered Silicates through Immobilization of Imidazolium Groups
Nobuyuki Takahashi, Hideo Hata, and Kazuyuki Kuroda
Chem. Mater., 23, 266-273 (2011).



Formation of Hierarchically Porous Hollow Spheres Composed of Dehydroxylated Imogolite and Carbonaceous Materials
Yoshiyuki Kuroda and Kazuyuki Kuroda
Bull. Chem. Soc. Jpn., 84, 49-51 (2011).



Expansion of Intertubular Mesopores of Imogolite Nanotubes by Thermal Decomposition of an Imogolite-Poly(sodium 4-styrenesulfonate) Composite
Yoshiyuki Kuroda and Kazuyuki Kuroda
Chem. Lett., 40, 46-48 (2011).



Papers Published in 2010


Effect of organic additives on the formation of alkylsiloxane mesophases
Atsushi Shimojima, Mikako Sakurai, Kazuyuki Kuroda, Tatsuya Okubo
J. Colloid Interface Sci., 350, 155-160 (2010).



Morphosynthesis of Nanostructured Gold Crystals by Utilizing Interstices in Periodically Arranged Silica Nanoparticles as a Flexible Reaction Field
Yoshiyuki Kuroda and Kazuyuki Kuroda
Angew. Chem. Int. Ed., 49, 6993-6997 (2010).



Tailored synthesis of mesoporous platinum replicas using double gyroid mesoporous silica (KIT-6) with different pore diameters via vapor infiltration of a reducing agent
Yoji Doi, Azusa Takai, Yasuhiro Sakamoto, Osamu Terasaki, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Commun., 46, 6365-6367 (2010).


Preparation of lamellar inorganic-organic hybrids from tetraethoxysilane and a coumarin derivative containing a triethoxysilyl group and photodimerization of the interlayer coumarin groups
Shintaro Nasu, Ayako Tsuchiya and Kazuyuki Kuroda
J. Mater. Chem., 20, 6688-6693 (2010).


Nonhydrolytic synthesis of branched alkoxysiloxane oligomers Si[OSiH(OR)2]4 (R=Me, Et)
Ryutaro Wakabayashi, Kazufumi Kawahara and Kazuyuki Kuroda
Angew. Chem. Int. Ed., 49, 5273 (2010).


Anion exchangeable layered silicates modified with ionic liquids on the interlayer surface
Nobuyuki Takahashi, Hideo Hata and Kazuyuki Kuroda
Chem. Mater., 22, 3340-3348 (2010).


Lamellar self-assembly of a porphyrin derivative possessing poly(ethylene oxide) methyl ether and the formation of a silica-porphyrin hybrid with tetraethoxysilane
Shintaro Nasu and Kazuyuki Kuroda
J. Colloid Interface Sci., 348, 446-451 (2010).


Soft-chemical approach of noble metal nanowires templated from mesoporous silica (SBA-15) through vapor infiltration of a reducing agent
Azusa Takai, Yoji Doi, Yusuke Yamauchi and and Kazuyuki Kuroda
J. Phys. Chem. C, 114, 7586-7593 (2010).


Electrochemical analysis of perpendicular mesoporous Pt electrode filled with pure water for clarifying the active region in fuel cell catalyst layers
Satoshi Tominaka, Chia-Wen Wu, Kazuyuki Kuroda and Tetsuya Osaka
J. Power Sources, 195, 2236-2240 (2010).


Interlayer modification of a layered H-octosilicate (H-RUB-18) with methanol: Formation of a highly ordered organosilicate nanohybrid
Shosuke Kiba, Tetsuro Itagaki, Teruyuki Nakato and Kazuyuki Kuroda
J. Mater. Chem., 20, 3202-3210 (2010).


Integrated structural control of cage-type mesoporous platinum possessing both tunable large mesopores and variable surface structures by block copolymer-assisted pt deposition in a hard-template
Yoshiyuki Kuroda, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Commun., 1827-1829 (2010).


Tailored electrochemical synthesis of 2D-hexagonal, lamellar, and cage-type mesostructured Pt thin films with extralarge periodicity
Azusa Takai, Yusuke Yamauchi and Kazuyuki Kuroda
J. Am. Chem. Soc., 132, 208-214 (2010).

Formation of Reactive Microporous Networks from Alkoxyvinylsilylated Siloxane Cages
Yoshiaki Hagiwara, Atsushi Shimojima, Kazuyuki Kuroda
Bull. Chem. Soc. Jpn., 83, 424-430 (2010).

Synthesis of Mesoporous Carbon Using a Fullerenol-based Precursor Solution via Nanocasting with SBA-15
Yoji Doi, Azusa Takai, Sho Makino, Logudurai Radhakrishnan, Norihiro Suzuki, Wataru Sugimoto, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Lett., 39, 777-779 (2010).


Papers Published in 2009


Alignment control of self-assembled organosiloxane films derived from alkyloligosiloxane amphiphiles
Jenny Du, Madoka Fukushima, Shigeru Sakamoto, Mikako Sakurai, Takashi Suzuki, Atsushi Shimojima, Hirokatsu Miyata, Cathleen M. Crudden and Kazuyuki Kuroda
Langmuir, 25, 13614-13618 (2009).


Ferromagnetic mesostructured alloys: Design of ordered mesostructured alloys with multicomponent metals from lyotropic liquid crystals
Yusuke Yamauchi, Masaki Komatsu, Minekazu Fuziwara, Yoshihiro Nemoto, Keisuke Sato, Tokihiko Yokoshima, Hiroaki Sukegawa, Kouichiro Inomata and Kazuyuki Kuroda
Angew. Chem. Int. Ed., 48, 7792-7797 (2009).


Dialysis process for the removal of surfactants to form colloidal mesoporous silica nanoparticles
Chihiro Urata, Yuko Aoyama, Akihisa Tonegawa, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Commun., 5094-5096 (2009).


Formation of Two- and Three-Dimensional Hybrid Mesostructures from Branched Siloxane Molecules
Shigeru Sakamoto, Atsushi Shimojima, Keiichi Miyasaka, Juanfang Ruan, Osamu Terasaki and Kazuyuki Kuroda
J. Am. Chem. Soc., 131, 9634-9635 (2009).

Preparation of Mesoporous Pt-Ru Alloy Fibers with Tunable Compositions via Evaporation-Mediated Direct Templating (EDIT) Method Utilizing Porous Anodic Alumina Membranes
Azusa Takai, Takahiro Saida, Wataru Sugimoto, Liang Wang, Yusuke Yamauchi and Kazuyuki Kuroda
Chem. Mater., 21, 3414-3423 (2009).


Self-Assembled Double Ladder Structure Formed Inside Carbon Nanotubes by Encapsulation of H8Si8O12
Zheng Liu, Soon-Kil Joung, Toshiya Okazaki, Kazu Suenaga, Yoshiaki Hagiwara, Tetsu Ohsuna, Kazuyuki Kuroda and Sumio Iijima
ACS Nano, 3, 1160-1166 (2009).


Facile formation of single crystalline Pt nanowires on a substrate utilising lyotropic liquid crystals consisting of cationic surfactants
Azusa Takai, Yusuke Yamauchi and Kazuyuki Kuroda
J. Mater. Chem., 19, 4205-4210 (2009).


Properties of metal species in square-shape mesopores of KSW-2-based silica
Tatsuo Kimura, Shengjun Huang, Atsushi Fukuoka and Kazuyuki Kuroda
J. Mater. Chem., 19, 3859-3866 (2009).


Mesostructured silica based delivery system for a drug with a peptide as a cell-penetrating vector
Chuanbo Gao, Isabel Izquierdo-Barba, Ikuhiko Nakase, Shiroh Futaki, Juanfang Ruan, Kazutami Sakamoto, Yasuhiro Sakamoto, Kazuyuki Kuroda, Osamu Terasaki and Shunai Che
Micropor. Mesopor. Mater., 122, 201-207 (2009).


Facile patterning of assembled silica nanoparticles with a closely packed arrangement through guided growth
Yusuke Yamauchi, Junko Imasu, Yoshiyuki Kuroda, Kazuyuki Kuroda, and Yoshio Sakka
J. Mater. Chem., 19, 1964-1967 (2009).


Ordered mesoporous silica derived from layered silicates
Tatsuo Kimura, and Kazuyuki Kuroda
Adv. Funct. Mater., 19, 511-527 (2009).


Color Tuning of an Acidic Blue Dye by Intercalation into the Basic Interlayer Galleries of a Poly(allylamine)/Synthetic Fluoromica Nanocomposite
Hideo Hata, Thomas E. Mallouk, and Kazuyuki Kuroda
Chem. Mater., 21, 985-993 (2009).


Papers Published in 2008


A hybrid mesoporous material with uniform distribution of carboxy groups assembled from a cubic siloxane-based precursor
R. Goto, A. Shimojima, H. Kuge, and K. Kuroda
Chem.Commun., 46, 6152-6154 (2008).


Exploration of a Standing Mesochannel System with Antimatter/Matter Atomic Probes
H. K. M. Tanaka, Y. Yamauchi, T. Kurihara, Y. Sakka, K. Kuroda, and A. P. Mills Jr.
Adv. Mater., 20(24), 4728-4733 (2008).


Self-Assembly of Amphiphilic Alkyloligosiloxanes within Cylindrically and Spherically Confined Spaces
M. Sakurai, A. Shimojima, Y. Yamauchi, and K. Kuroda
Langmuir, 24, 13121-13126 (2008).


Magnetically induced orientation of mesochannels inside porous anodic alumina membranes under ultra high magnetic field of 30 T: Confirmation by TEM
Y. Yamauchi, A. Sugiyama, M. Sawada, M. Komatsu, A. Takai, C. Urata, N. Hirota, Y. Sakka, and K. Kuroda
J. Ceram. Soc. Japan., 116, 1244-1248 (2008).


Self-Assembly of Alkyl-Substituted Cubic Siloxane Cages into Ordered Hybrid Materials
A. Shimojima, R. Goto, N. Atsumi, and K. Kuroda
Chem. Eur. J., 14, 8500-8506 (2008).


Layer-by-Layer Assembly of Imogolite Nanotubes and Polyelectrolytes into Core-shell Particles and Their Conversion to Hierarchically Porous Spheres
Y. Kuroda, and K. Kuroda
Sci. Technol. Adv. Mater., 9, 025018 (2008).


Fabrication of mesoporous Pt nanotubes utilizing dual templates under a reduced pressure condition
A. Takai, Y. Yamauchi, and K. Kuroda
Chem. Commun., 35, 4171-4173 (2008).


Organic derivatives of the layered perovskite HLaNb2O7・xH2O with polyether chains on the interlayer surface: characterization, intercalation of LiClO4, and ionic conductivity
Y. Takeda, T. Momma, T. Osaka, K. Kuroda, and Y. Sugahara
J. Mater. Chem., 18, 3581-3587 (2008).


Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture
K. Kawahara, Y. Hagiwara, A. Shimojima, and K. Kuroda
J. Mater. Chem., 18, 3193-3195 (2008).


Mesoporous Platinum with Giant Mesocages Templated from Lyotropic Liquid Crystals Consisting of Diblock Copolymers
Y. Yamauchi, A. Sugiyama, R. Morimoto, A. Takai, and K. Kuroda
Angew. Chem. Int. Ed., 47, 5371-5373 (2008).


Facile unidirectional alignment of mesochannels in a mesoporous silica film on a freshly cleaved mica surface
T. Suzuki, Y. Kanno, Y. Morioka, and K. Kuroda
Chem. Commun., 28, 3284-3286 (2008).


Perpendicular mesoporous Pt thin films: electrodeposition from titania nanopillars and their electrochemical properties
S. Tominaka, C.-W. Wu, T. Momma, K. Kuroda, and T. Osaka
Chem. Commun., 25, 2888-2890 (2008).


Fabrication of Hierarchically Porous Spherical Particles by Assembling Mesoporous Silica Nanoparticles via Spray Drying
C. Urata, Y. Yamauchi, Y. Aoyama, J. Imasu, S. Todoroki, Y. Sakka, S. Inoue, and K. Kuroda
J. Nanosci. Nanotechnol., 8, 3101-3105 (2008).


Pt Fibers with Stacked Donut-Like Mesospace by Assembling Pt Nanoparticles:Guided Deposition in Physically Confined Self-Assembly of Surfactants
Y. Yamauchi, A. Takai, T. Nagaura, S. Inoue, and K. Kuroda
J. Am. Chem. Soc., 130, 5426-5427 (2008).


Rational Design of Mesoporous Metals and Related Nanomaterials by a Soft-Templating Approach
Y. Yamauchi, and K. Kuroda
Chem. Asian. J., 3, 664-676 (2008).


Oligomeric Alkoxysilanes Possessing Cage-like Hybrid as Cores: Designed Precursors of Nanohybrid Materials
H. Kuge, Y. Hagiwara, A. Shimojima, and K. Kuroda
Chem. Asian J., 3, 600-606 (2008).


Phenylene-bridged mesoporous organosilica films with uniaxially aligned mesochannels
T. Suzuki, H. Miyata, and K. Kuroda
J. Mater. Chem., 18, 1239-1244 (2008).


Platinum Thin Film Consisting of Well-Aligned Nanowires and Its Optical Behavior
T. Suzuki, H. Miyata, T. Noma, and K. Kuroda
J. Phys. Chem. C, 112, 1831-1836 (2008).


Alkoxysililated-Derivatives of Double-Four-Ring Silicates as Novel Building Blocks of Silica-Based Materials
Y. Hagiwara, A. Shimojima, and K. Kuroda
Chem. Mater., 20, 1147-1153 (2008).


Silica Films Having Zigzag Mesoporous Structures with Fixed Kink Angles
H. Miyata, T. Suzuki, M. Watanabe, T. Noma, K. Takada, T. Mukaide, and K. Kuroda
Chem. Mater., 20, 1082-1089 (2008).


Vapor Infiltration of a Reducing Agent for Facile Synthesis of Mesoporous Pt and Pt-Based Alloys and Its Application for the Preparation of Mesoporous Pt Microrods in Anodic Porous Membranes
Y. Yamauchi, A. Takai, M. Komatsu, M. Sawada, T. Ohsuna, and K. Kuroda
Chem. Mater., 20, 1004-1011 (2008).


Design of Molecularly Ordered Framework of Mesoporous Silica with Squared One-Dimensional Channels
T. Kimura, H. Tamura, M. Tezuka, D. Mochizuki, T. Shigeno, T. Ohsuna, and K. Kuroda
J. Am. Chem. Soc., 130, 201-209 (2008).


Stable Silanetriols That Contain tert-Alkoxy Groups: Versatile Precursors of Siloxane-Based Nanomaterials
J. Suzuki, A. Shimojima, Y. Fujimoto, and K. Kuroda
Chem. Eur. J., 14, 973-980 (2008).


Cycle and Rate Properties of Mesoporous Tin Anode for Lithium Ion Secondary Batteries
H. Nara, Y. Fukuhara, A. Takai, M. Komatsu, H. Mukaibo, Y. Yamauchi, T. Momma, K. Kuroda, and T. Osaka
Chem. Lett., 37, 142-143 (2008).

Book sections

メソ多孔体の作製
若林隆太郎,浦田千尋,黒田一幸
ゾル-ゲル法技術の最新動向(第9章)、シーエムシー出版 (2010)

ナノスケールでのハニカム構造の設計―メソポーラスシリカ(シリカメソ多孔体)―
浦田 千尋、黒田 一幸
ハニカム構造の応用と機能―ハニカム構造材料からナノハニカム構造まで―(第II編、第2章)、シーエムシー出版 (2008)

自己組織化によるメソ構造体の合成
下嶋 敦,黒田 一幸
シルセスキオキサン材料の化学と応用展開(第5章)、シーエムシー出版 (2008)

自己組織化によるシリカ系メソ構造体の直接合成
下嶋 敦,黒田 一幸
ゾル-ゲル法のナノテクノロジーへの応用(第1章 第5節)、シーエムシー出版 (2005)

無機ナノシートの科学と応用
監修 黒田一幸,佐々木高義
シーエムシー出版 (2005)

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  • 各務記念材料技術研究所
早稲田大学 先進理工学部 応用化学科 無機合成化学分野 黒田一幸 研究室
東京都新宿区大久保3-4-1 早稲田大学 西早稲田キャンパス 65-405B室
The Kuroda Group, Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Japan